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Antimony

Synonyms & Trade Names
Antimony metal, Antimony powder, Stibium
CAS No.
7440-36-0
RTECS No.
CC4025000
DOT ID & Guide
1549 157 (inorganic compounds, n.o.s.)
2871 170 (powder)
3141 157 (inorganic liquid compounds, n.o.s.)
Formula
Sb
Conversion
IDLH
50 mg/m3 (as Sb)
See: 7440360
Exposure Limits
NIOSH REL
*: TWA 0.5 mg/m3 [*Note: The REL also applies to other antimony compounds (as Sb).]
OSHA PEL
*: TWA 0.5 mg/m3 [*Note: The PEL also applies to other antimony compounds (as Sb).]
Measurement Methods

NIOSH 7301 , 7303 , P&CAM261 (II-4);
OSHA ID121 , ID125G , ID206
See: NMAM or OSHA Methods
Physical Description
Silver-white, lustrous, hard, brittle solid; scale-like crystals; or a dark-gray, lustrous powder.
MW:
121.8
BP:
2975°F
MLT: 1166°F
Sol:
Insoluble
VP:
0 mmHg (approx)
IP:
NA
Sp.Gr:
6.69
Fl.P:
NA
UEL:
NA
LEL:
NA
Noncombustible Solid in bulk form, but a moderate explosion hazard in the form of dust when exposed to flame.
Incompatibilities & Reactivities
Strong oxidizers, acids, halogenated acids [Note: Stibine is formed when antimony is exposed to nascent (freshly formed) hydrogen.]
Exposure Routes
inhalation, ingestion, skin and/or eye contact
Symptoms
irritation eyes, skin, nose, throat, mouth; cough; dizziness; headache; nausea, vomiting, diarrhea; stomach cramps; insomnia; anorexia; unable to smell properly
Target Organs
Eyes, skin, respiratory system, cardiovascular system
Personal Protection/Sanitation
(See protection codes)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: Daily
First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations

NIOSH/OSHA

Up to 5 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100.
Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator

Up to 12.5 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered, air-purifying respirator with a high-efficiency particulate filter.

Up to 25 mg/m3:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece

Up to 50 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode

Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus

Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
Any appropriate escape-type, self-contained breathing apparatus

Important additional information about respirator selection

See also: INTRODUCTION   See ICSC CARD: 0775
 
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