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Rhodium (metal fume and insoluble compounds, as Rh)

Synonyms & Trade Names
Rhodium metal: Elemental rhodium
Synonyms of other insoluble rhodium compounds vary depending upon the specific compound.
CAS No.
7440-16-6 (metal)
RTECS No.
VI9069000 (metal)
DOT ID & Guide
Formula
Rh (metal)
Conversion
IDLH
100 mg/m3 (as Rh)
See: rhodium
Exposure Limits
NIOSH REL
: TWA 0.1 mg/m3
OSHA PEL
: TWA 0.1 mg/m3
Measurement Methods

NIOSH S188 (II-3)
See: NMAM or OSHA Methods
Physical Description
Metal: White, hard, ductile, malleable solid with a bluish-gray luster.
MW:
102.9
BP:
6741°F		 MLT: 3571°F
Sol:
Insoluble
VP:
0 mmHg (approx)
IP:
NA
Sp.Gr:
12.41 (metal)
Fl.P:
NA
UEL:
NA
LEL:
NA
Metal: Noncombustible Solid in bulk form, but flammable as dust or powder.
Incompatibilities & Reactivities
Chlorine trifluoride, oxygen difluoride
Exposure Routes
inhalation
Symptoms
Possible resp sensitization
Target Organs
respiratory system
Personal Protection/Sanitation
(See protection codes)
Skin: No recommendation
Eyes: No recommendation
Wash skin: No recommendation
Remove: No recommendation
Change: No recommendation
First Aid
(See procedures)


Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations

NIOSH/OSHA

Up to 0.5 mg/m3:
(APF = 5) Any quarter-mask respirator.
Click here for information on selection of N, R, or P filters.

Up to 1 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100.
Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator

Up to 2.5 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered, air-purifying respirator with a high-efficiency particulate filter.

Up to 5 mg/m3:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece

Up to 100 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode

Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus

Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
Any appropriate escape-type, self-contained breathing apparatus

Important additional information about respirator selection

See also: INTRODUCTION   See ICSC CARD: 1247
 

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