Documentation for Immediately Dangerous To Life or Health Concentrations (IDLHs)
Rhodium (soluble compounds, as Rh)
CAS number: Varies
NIOSH REL: 0.001 mg/m3 TWA
Current OSHA PEL: 0.001 mg/m3 TWA
1989 OSHA PEL: Same as current PEL
1993-1994 ACGIH TLV: 0.01 mg/m3 TWA
Description of substance Varies
Original (SCP) IDLH*: No evidence [*Note: "Effective" IDLH = 2 mg Rh/m3 -- see discussion below.]
Basis for original (SCP) IDLH: There is no indication from experimental data or industrial experience that the soluble compounds of rhodium produce toxic effects in man. Therefore, because no evidence of an IDLH exists, respirators have been selected on the basis of the assigned protection factor afforded by each device up to 2,000 ´ the OSHA PEL of 0.001 mg Rh/m3 (i.e., 2 mg Rh/m3); only the "most protective" respirators are permitted for use in concentrations exceeding 2 mg Rh/m3.
Short-term exposure guidelines: None developed
ACUTE TOXICITY DATA:
Animal or human data: None relevant for use in determining
the revised IDLH.
|Revised IDLH: 2 mg Rh/m3
Basis for revised IDLH: The available toxicological data contain no evidence that an acute exposure to a high concentration of soluble rhodium compounds would impede escape or cause any irreversible health effects within 30 minutes. However, the revised IDLH for soluble rhodium compounds is 2 mg Rh/m3 based on being 2,000 times the NIOSH REL and OSHA PEL of 0.001 mg Rh/m3 (2,000 is an assigned protection factor for respirators and was used during the Standards Completion Program for deciding when the "most protective" respirators should be used for soluble rhodium compounds).
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