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Methyl parathion

Synonyms & Trade Names
Azophos®; O,O-Dimethyl-O-p-nitrophenylphosphorothioate; Parathion methyl
CAS No.
298-00-0
RTECS No.
TG0175000
DOT ID & Guide
2783 152 (solid)
3018 152 (liquid)
Formula
(CH3O)2P(S)OC6H4NO2
Conversion
IDLH
N.D.
See: IDLH INDEX
Exposure Limits
NIOSH REL
: TWA 0.2 mg/m3 [skin]
OSHA PEL
: none
Measurement Methods

NIOSH 5600;
OSHA PV2112
See: NMAM or OSHA Methods
Physical Description
White to tan, crystalline solid or powder with a pungent, garlic-like odor. [pesticide] [Note: The commercial product in xylene is a tan liquid.]
MW:
263.2
BP:
289°F
MLT: 99°F Sol(77°F): 0.006%
VP:
0.00001 mmHg
IP:
?
Sp.Gr:
1.36
Fl.P:
?
UEL:
?
LEL:
?
Combustible Solid
Incompatibilities & Reactivities
Strong oxidizers, water [Note: Explosive risk when heated above 122°F.]
Exposure Routes
inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms
irritation eyes, skin; nausea, vomiting, abdominal cramps, diarrhea, salivation; headache, dizziness, lassitude (weakness, exhaustion); rhinorrhea (discharge of thin nasal mucus), chest tightness; blurred vision, miosis; cardiac irreg; muscle fasciculation; dyspnea (breathing difficulty)
Target Organs
Eyes, skin, respiratory system, central nervous system, cardiovascular system, blood cholinesterase
Personal Protection/Sanitation
(See protection codes)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated/Daily
Remove: When wet or contaminated
Change: Daily
Provide: Eyewash, Quick drench
First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations

NIOSH

Up to 2 mg/m3:
(APF = 10) Any air-purifying half-mask respirator with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100, P100.
Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator

Up to 5 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered, air-purifying respirator with an organic vapor cartridge in combination with a high-efficiency particulate filter.

Up to 10 mg/m3:
(APF = 50) Any air-purifying full-facepiece respirator equipped with organic vapor cartridge(s) in combination with an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece

Up to 200 mg/m3:
(APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode

Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus

Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter.
Click here for information on selection of N, R, or P filters.
Any appropriate escape-type, self-contained breathing apparatus

Important additional information about respirator selection

See also: INTRODUCTION   See ICSC CARD: 0626
 
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