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Stibine

RTECS #: WJ0700000

CAS #: 7803-52-3


UPDATE: May 2009 MW: 124.78 MF: H3Sb


NOTE:

TABLE OF CONTENTS:
  1. SYNONYMS:
  2. ACUTE TOXICITY DATA:
  3. REVIEWS:
  4. STANDARDS AND REGULATIONS:
  5. NIOSH DOCUMENTATION AND SURVEILLANCE:
  6. STATUS IN FEDERAL AGENCIES:
  7. REFERENCES:

SYNONYMS:

  1. Antimonwasserstoffes (German)
  2. Antimony hydride
  3. Antimony trihydride
  1. Antymonowodor (Polish)
  2. Hydrogen antimonide
  3. Stibine (ACGIH:OSHA)


SKIN AND EYE IRRITATION DATA AND REFERENCES:

ROUTE/
ORGANISM
DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R


MUTATION DATA AND REFERENCES:

SYSTEM TEST ROUTE/
ORGANISM/
TISSUE
DOSE REFERENCE
N/R N/R N/R N/R


REPRODUCTIVE EFFECTS DATA AND REFERENCES:

ROUTE/
ORGANISM
DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R


TUMORIGENIC DATA AND REFERENCES:

ROUTE/
ORGANISM
DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R


ACUTE TOXICITY DATA AND REFERENCES:

ROUTE/
ORGANISM
DOSE
EFFECT

REFERENCE
inhalation
cat
lowest published lethal concentration: 40 ppm/1 hour Lung, Thorax, or Respiration: Acute pulmonary edema JIHTAB 28,167,1946
inhalation
cat
lowest published lethal concentration: 500 mg/m3/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
dog
lowest published lethal concentration: 40 ppm/1 hour Lung, Thorax, or Respiration: Acute pulmonary edema JIHTAB 28,167,1946
inhalation
dog
lowest published lethal concentration: 500 mg/m3/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
dog
lowest published lethal concentration: 200 mg/m3/1 hour Kidney, Ureter, and Bladder: Hematuria

Blood: Other hemolysis with or without anemia
VCVN5* -,105,1993
inhalation
guinea pig
lowest published lethal concentration: 92 ppm/1 hour Kidney, Ureter, and Bladder: Changes in tubules (including acute renal failure, acute tubular necrosis) 28ZLA8 -,30,1961
inhalation
guinea pig
lowest published lethal concentration: 500 mg/m3/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
mammal (species unspecified)
lowest published lethal concentration: 1 pph N/R VCVN5* -,105,1993
inhalation
mouse
lowest published lethal concentration: 100 ppm/1 hour N/R 28ZLA8 -,30,1961
inhalation
mouse
lowest published lethal concentration: 500 mg/m3/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
rabbit
lowest published lethal concentration: 500 mg/m3/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993


OTHER MULTIPLE DOSE DATA AND REFERENCES:

ROUTE/
ORGANISM
DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R


REVIEWS:

ORGANIZATION STANDARD
REFERENCE

American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value time-weighted average 0.1 ppm DTLVS* TLV/BEI,2007
TOXICOLOGY REVIEW
HBTME* ,353,2007


STANDARDS AND REGULATIONS:

ORGANIZATION STANDARD
REFERENCE

Mine Safety and Health Administration (MSHA) STANDARD - air time-weighted average 0.1 ppm (0.5 mg/m3) DTLVS* 3,233,1971
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (General Industry) 8 hour time-weighted average 0.1 ppm (0.5 mg/m3) CFRGBR 29,1910.1000,1994
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Construction) 8 hour time-weighted average 0.1 ppm (0.5 mg/m3) CFRGBR 29,1926.55,1994
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Shipyards) 8 hour time-weighted average 0.1 ppm (0.5 mg/m3) CFRGBR 29,1915.1000,1993
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Federal Contractors) 8 hour time-weighted average 0.1 ppm (0.5 mg/m3) CFRGBR 41,50-204.50,1994
Occupational Exposure Limit - AUSTRALIA time-weighted average 0.1 ppm (0.51 mg/m3), JUL2008
Occupational Exposure Limit - BELGIUM time-weighted average 0.1 ppm (0.52 mg/m3), MAR2002
Occupational Exposure Limit - DENMARK time-weighted average 0.05 ppm (0.25 mg/m3), OCT 2002
Occupational Exposure Limit - DENMARK time-weighted average 0.5 mg(Sb)/m3, OCT 2002
Occupational Exposure Limit - FRANCE VME 0.1 ppm (0.5 mg/m3), FEB2006
Occupational Exposure Limit - HUNGARY time-weighted average 0.5 mg/m3, short term exposure limit 2 mg/m3, SEP2000
Occupational Exposure Limit - KOREA time-weighted average 0.1 ppm (0.5 mg/m3), 2006
Occupational Exposure Limit - MEXICO time-weighted average 0.1 ppm (0.5 mg/m3);
short term exposure limit 0.3 ppm (1.5 mg/m3), 2004
Occupational Exposure Limit - MEXICO time-weighted average 0.5 mg(Sb)/m3, 2004
Occupational Exposure Limit - THE NETHERLANDS MAC-TGG 0.5 mg(Sb)/m3, 2003
Occupational Exposure Limit - THE NETHERLANDS MAC-TGG 0.5 mg/m3, 2003
Occupational Exposure Limit - NEW ZEALAND time-weighted average 0.1 ppm (0.51 mg/m3), JAN2002
Occupational Exposure Limit - NORWAY time-weighted average 0.05 ppm (0.25 mg/m3), JAN1999
Occupational Exposure Limit - POLAND MAC(time-weighted average) 0.2 mg/m3, MAC(short term exposure limit) 1.5 mg/m3, JAN1999
Occupational Exposure Limit - RUSSIA time-weighted average 0.2 mg(Sb)/m3, short term exposure limit 0.5 mg(Sb)/m3, JUN2003
Occupational Exposure Limit - SWEDEN time-weighted average 0.05 ppm (0.3 mg/m3), JUN2005
Occupational Exposure Limit - SWITZERLAND MAK- week 0.1 ppm (0.5 mg/m3);
KZG- week 0.1 ppm (0.5 mg/m3),DEC2006
Occupational Exposure Limit - UNITED KINGDOM time-weighted average 0.5 mg(Sb)/m3, 2005


NIOSH DOCUMENTATION AND SURVEILLANCE:

ORGANIZATION STANDARD or SURVEY
REFERENCE

National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO STIBINE-air 10 hour time-weighted average 0.1 ppm NIOSH* DHHS #92-100,1992
National Occupational Exposure Survey 1983 National Occupational Exposure Survey 1983: Hazard Code: X5764;
Number of Industries 1;
Total Number of Facilities 23;
Number of Occupations 1;
Total Number of Employees Exposed 23


STATUS IN FEDERAL AGENCIES:

ORGANIZATION
REFERENCE

NIOSH Analytical Method, 1994: Stibine, 6008


REFERENCES:

CODEN
REFERENCE

28ZLA8 "Toxicity of Industrial Metals," Browning, E., London, Butterworths, 1961
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996
HBTME*
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU.
NIOSH* National Institute of Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda.
VCVN5* "Vrednie chemichescie veshestva. Neorganicheskie soedinenia elementov V-VII groopp" (Hazardous substances. Inornanic substances containing V-VII group elements), Bandman A.L. et al., Chimia, 1989.

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