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Ten-cycle bench-scale study of simplified clay-hydrogen chloride process for alumina production.

Shanks DE

Reno, NV: U.S. Department of the Interior, Bureau of Mines, RI 9544, 1995 Jan; :1-26

https://ntrl.ntis.gov/NTRL/dashboard/searchResults/titleDetail/PB95217071.xhtml

20039176

This research simplified an earlier hydrogen chloride (HC1) leach-sparge process developed by the U.S. Bureau of Mines to recover reduction-grade alumina from domestic kaolin clay. Improvements were made by decreasing the initial leaching acid concentration from 25 to 20 pct, decreasing the leaching time from 1-2 h to 15-30 min, eliminating the solvent extraction step for Fe removal, and eliminating the step to recover the Al content of the bleedstream circuit. A 10-cycle bench-scale experiment of the simplified process showed that the FeCl3 concentration built up to 9.3 g/L in the recycle stream. This did not interfere with any of the unit operations or final alumina product purity because Fe forms stable soluble chloride complexes when sparged with HC1 and is easily washed from the large aluminum chloride hexahydrate (ACH) crystals. The reduced leaching time and acid concentration did not decrease Al extraction.

Clay-minerals; Solvents; Extraction; Hydrochloric-acid; Concentration-composition; Crystallizers; Hydrogen-chloride; Aluminum-oxide; Materials-recovery; Kaolin; Leaching

19950101

Report of Investigations

1995

PB95-217071

A03

RI-9544

RERC

Reno, NV: U.S. Department of the Interior, Bureau of Mines, RI 9544

NV