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A comparison of solid sampler methods for the determination of hexamethylene-based isocyanates in spray-painting operations.

Authors
Rudzinski WE; Yin J; England E; Carlton G; Key-Schwartz RJ; Lesage J
Source
Am Ind Hyg Assoc J 2001 Mar/Apr; 62(2):246-50
NIOSHTIC No.
20021856
Abstract
A polyurethane foam sponge impregnated with 1-(2-methoxyphenyl) piperazine in dimethylsulfoxide was mounted in both cassette and inhalable organic monitor samplers and these were then compared with a dual-filter cassette. The samplers were used for the collection of hexamethylene diisocyanate (HDI) monomer and oligomers during actual spray-painting operations. The dual filter cassettes were positioned on a mannequin. The polyurethane foam cassette (PUF CAS) and polyurethane foam inhalable organic monitor (PUF IOM) samplers were positioned on a cart in the same maximum overspray area. Data from this pilot study suggest that there is no significant difference (P < 0.05, n = 6) in the amount of HDI monomer obtained with the PUF IOM sampler when compared with the amount obtained from the dual filter cassette. The data also suggest that the PUF IOM sampler yields a higher amount of HDI oligomer than either the dual filter cassette or the PUF CAS sampler, neither of which exhibited a significant difference (P < 0.05, n = 6) from each other.
Keywords
Sampling-methods; Spray-painting; Inhalants; Filters; Samplers; Sampling; Isocyanates; Paint-spraying; Author Keywords: dual cassette sampler; isocyanates; 1-(2-methoxyphenyl) piperazine; PUF cassette sampler; PUF IOM sampler; spray painting
CODEN
AIHAAP
CAS No.
110-82-7; 67-68-5
Publication Date
20010301
Document Type
Journal Article
Editors
Halley PD
Funding Type
Grant
Fiscal Year
2001
Identifying No.
Grant-Number-R01-OH-003295
Issue of Publication
2
ISSN
0002-8894
NIOSH Division
DART
Priority Area
Intervention Effectiveness Research; Surveillance Research Methods
Source Name
American Industrial Hygiene Association Journal
State
TX; OH
Performing Organization
Texas State University - San Marcos
Page last reviewed: May 5, 2020
Content source: National Institute for Occupational Safety and Health Education and Information Division