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Inherent oxidation protection of Fe-5Cr-15Ni-2Si-4.5Mo.

Authors
Rawers-JC
Source
Oxid Met 1987 Oct; 28(3-4):183-194
Link
http://dx.doi.org/10.1007/BF00656706
NIOSHTIC No.
10011843
Abstract
The oxidation mechanism of Fe-5Cr-15Ni-2Si-4.5Mo alloy was investigated in order to determine the role of Si and Mo in providing oxidation resistance. It was determined that the oxidation protection in the temperature range 750-950 degrees C resulted from formation of a continuous oxide sublayer of SiO2 (or possibly Fe2 SiO4).Molybdenum formed an intermetallic Fe2 Mo 1-x Si x that eventually diffused out into the grain boundaries and formed a protective barrier to the oxidation process. The mechanism behind the improved oxidation is the formation of a SiO2 layer at the metal-oxide interface that retards the outward diffusion of Fe. It was also established that the oxidation mechanism was controlled by an activation energy equal to that of Fe3+ ions diffusing through SiO2.
Keywords
Oxidative-processes; Oxidation; Iron-oxides; Iron-compounds; Nickel-compounds; Metal-compounds; Metallic-compounds; Chemical-reactions; Chemical-kinetics
CODEN
OXMEAF
Publication Date
19871001
Document Type
OP; Journal Article
Fiscal Year
1988
Identifying No.
OP 46-88
Issue of Publication
3-4
ISSN
0030-770X
NIOSH Division
ALRC
Source Name
Oxidation of Metals
State
OR
Page last reviewed: March 11, 2019
Content source: National Institute for Occupational Safety and Health Education and Information Division