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Equilibrium Composition of Simulated Coal Combustion Products: Relationship to Fireside Corrosion and Ash Fouling.

Authors
Wilson JS; Redifer MW
Source
Trans Asme J Eng for Power 1974 Apr; 96(2):145-152
Link
https://doi.org/10.1115/1.3445763
NIOSHTIC No.
10010923
Abstract
A computer solution of chemical equilibrium composition is presented for high-temperature combustion reactions related to fireside corrosion and ash fouling. A simple calculation system, which models the injection of a sodium-potassium mixture through a flame, is solved for equilibrium compositions of temperatures from 1,500 deg. to 3,000 deg. F at oxygen levels in the gas stream ranging from 0.1 to 17 percent and 1 atmosphere pressure. At equilibrium, principally alkali sulfates and hydroxides are produced in the model of a combustion product atmosphere resembling that in a coal-fired boiler. A total of 42 reactions involving 40 chemical species were treated in the reactant mixture, and compositions for the entire system are included.
Publication Date
19740401
Document Type
OP;
Fiscal Year
1974
Identifying No.
OP 119-74
Issue of Publication
2
Source Name
Trans. ASME, J. Eng. for Power, V. 96, Ser. A, No. 2, April 1974, PP. 145-152
Page last reviewed: December 23, 2021
Content source: National Institute for Occupational Safety and Health Education and Information Division