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Determination of Carbonate Minerals of Green River Formation Oil Shales, Piceance Creek Basin, Colorado.

Young NB; Smith JW; Robb WA
NTIS: PB 240 669 :41 pages
Carbonate minerals constitute a major fraction of the oil shale in Colorado's Green River Formation. Quantification of carbonate minerals is important for the characterization of oil shale, particularly because of their thermal activity in production of oil from shale. The carbonate minerals found in this oil shale are nahcolite (nahco3), dawsonite [naal(oh)2co3], dolomite [mg1-x fex)ca(co3)2], calcite (caco3), and ferroan [(mg1-x fex)co3]. Although carbonate minerals can be removed by acid extraction from the balance of the oil shale, direct determination of carbonate minerals is complicated by the occurrence of the same cations in more than one mineral. A method for assigning the acid-soluble cations to the individual carbonate minerals was developed from two assumptions based on oil shale geochemistry: (1) calcite and ferroan do not occur together, and (2) the ratio of iron and magnesium is the same in dolomite and ferroan. These assumptions were tested by the Bureau of Mines by applying the technique for assigning cations to 219 samples from the saline section of the formation. The reported carbonate mineral amounts were compared statistically with x-ray diffraction peak heights, verifying the cation assignment method.
Publication Date
Document Type
IH; Report of Investigation;
Fiscal Year
NTIS Accession No.
NTIS Price
Identifying No.
RI 8008
NIOSH Division
Source Name
NTIS: PB 240 669
Page last reviewed: December 3, 2021
Content source: National Institute for Occupational Safety and Health Education and Information Division