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Citrate-process Pilot-plant Operation At the Bunker Hill Company.

Crocker L; Martin DA; Nissen WI
NTIS: PB 80-122708 :77 pages
A goal of the federal Bureau of Mines is to minimize the undesirable environmental conflicts and impacts associated with mineral processing operations. To help reach this goal the Bureau operated a citrate-process pilot plant for the removal of sulfur dioxide from lead smelter sintering machine waste gases to test the process. The process uses a carboxylate solution such as citric acid to absorb sulfur dioxide from waste gases. The absorbed sulfur dioxide is subsequently reacted with hydrogen sulfide to precipitate sulfur and regenerate the solution for recycle. Nominal capacity of the pilot plant was 1,000 scfm of 0.5 Vol-pct sulfur dioxide gas. The pilot plant was operated for over 5,400 hr and produced about 55 net tons of sulfur. The operation demonstrated that (1) 99 pct of the sulfur dioxide could be removed from lead smelter sintering machining waste gases containing from 0.1 to 0.6 Vol-pct sulfur dioxide, (2) sulfur precipitation and solution regeneration with hydrogen sulfide in conventional stirred vessels was readily controlled, (3) precipitated sulfur could be continuously recovered as a 99.5-Pct- pure product by flotation and melting, and (4) 78 dry-vol-pct hydrogen sulfide gas could be produced from pilot-plant product sulfur, natural gas, and steam.
Publication Date
Document Type
IH; Report of Investigation;
Fiscal Year
NTIS Accession No.
NTIS Price
Identifying No.
RI 8374
NIOSH Division
Source Name
NTIS: PB 80-122708
Page last reviewed: December 3, 2021
Content source: National Institute for Occupational Safety and Health Education and Information Division