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Thermal Reactions of Shale-oil Components: Plant Pigments as Probable Precursors of Nitrogenous Compouunds in Shale Oil.

Jackson LP; Decora AW
NTIS: PB 241 216 :22 pages
As part of the current research effort in shale-oil chemistry conducted by the federal Bureau of Mines, reduced chlorophyllins were prepared and pyrolyzed in an effort to identify the role of plant pigments and their decomposition products in the nitrogenous compounds found in the product of oil-shale pyrolysis. The properties of the chlorophyllin pyrolysates were related to the composition of the reduced chlorophyllins with particular emphasis on the amount and types of nitrogen compounds formed. A comparison based on the types of nitrogen compounds present was made between shale oil and the chlorophyllin pyrolysates. To make this comparison, a sample of shale-oil light distillate was separated into polar and nonpolar fractions, and a careful examination of the polar fraction was conducted to obtain an accurate picture of the types of nitrogen compounds present. The information gathered from these studies was used to evaluate reduced chlorophyllin as a model of oil-shale kerogen insofar as the production of nitrogen compounds was concerned. The results indicate that the reduced chlorophyllin does yield nitrogen products that are directly related to the nitrogenous compounds in shale oil, and it therefore represents a good model of shale-oil kerogen. Work done in cooperation with the University of Wyoming.
Publication Date
Document Type
IH; Report of Investigation;
Fiscal Year
NTIS Accession No.
NTIS Price
Identifying No.
RI 8018
NIOSH Division
Source Name
NTIS: PB 241 216
Page last reviewed: November 26, 2021
Content source: National Institute for Occupational Safety and Health Education and Information Division