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Inhibition of Spontaneous Combustion of Coal.

Smith AC; Miron Y; Lazzara CP
MISSING :16 pages
This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (sht's) of the dried coal- additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum sht's of the mixtures, or by the time required for the sample temperature to reach 150 degrees c, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.
Publication Date
Document Type
IH; Report of Investigations;
Fiscal Year
Identifying No.
RI 9196
NIOSH Division
Source Name
Page last reviewed: November 19, 2021
Content source: National Institute for Occupational Safety and Health Education and Information Division