RTECS:WJ0700000 The Registry of Toxic Effects of Chemical Substances

Stibine

RTECS #: WJ0700000

CAS #: 7803-52-3

UPDATE: May 2009 MW: 124.78 MF: H₃Sb

NOTE:

TOXICITY DATA HAVE NOT BEEN EVALUATED. OMISSION OF A SUBSTANCE OR NOTATION DOES NOT IMPLY ANY RELIEF FROM REGULATORY RESPONSIBILITY.

TABLE OF CONTENTS:

SYNONYMS:

ACUTE TOXICITY DATA:

REVIEWS:

STANDARDS AND REGULATIONS:

NIOSH DOCUMENTATION AND SURVEILLANCE:

STATUS IN FEDERAL AGENCIES:

REFERENCES:

SYNONYMS:

Antimonwasserstoffes (German)

Antimony hydride

Antimony trihydride

Antymonowodor (Polish)

Hydrogen antimonide

Stibine (ACGIH:OSHA)

SKIN AND EYE IRRITATION DATA AND REFERENCES:
ROUTE/
ORGANISM DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R

MUTATION DATA AND REFERENCES:
SYSTEM TEST ROUTE/
ORGANISM/
TISSUE DOSE REFERENCE
N/R N/R N/R N/R

REPRODUCTIVE EFFECTS DATA AND REFERENCES:
ROUTE/
ORGANISM DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R

TUMORIGENIC DATA AND REFERENCES:
ROUTE/
ORGANISM DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R

ACUTE TOXICITY DATA AND REFERENCES:
ROUTE/
ORGANISM DOSE
EFFECT

REFERENCE
inhalation
cat lowest published lethal concentration: 40 ppm/1 hour Lung, Thorax, or Respiration: Acute pulmonary edema JIHTAB 28,167,1946
inhalation
cat lowest published lethal concentration: 500 mg/m³/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
dog lowest published lethal concentration: 40 ppm/1 hour Lung, Thorax, or Respiration: Acute pulmonary edema JIHTAB 28,167,1946
inhalation
dog lowest published lethal concentration: 500 mg/m³/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
dog lowest published lethal concentration: 200 mg/m³/1 hour Kidney, Ureter, and Bladder: Hematuria

Blood: Other hemolysis with or without anemia VCVN5* -,105,1993
inhalation
guinea pig lowest published lethal concentration: 92 ppm/1 hour Kidney, Ureter, and Bladder: Changes in tubules (including acute renal failure, acute tubular necrosis) 28ZLA8 -,30,1961
inhalation
guinea pig lowest published lethal concentration: 500 mg/m³/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
mammal (species unspecified) lowest published lethal concentration: 1 pph N/R VCVN5* -,105,1993
inhalation
mouse lowest published lethal concentration: 100 ppm/1 hour N/R 28ZLA8 -,30,1961
inhalation
mouse lowest published lethal concentration: 500 mg/m³/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993
inhalation
rabbit lowest published lethal concentration: 500 mg/m³/20 minute Lung, Thorax, or Respiration: Acute pulmonary edema VCVN5* -,105,1993

OTHER MULTIPLE DOSE DATA AND REFERENCES:
ROUTE/
ORGANISM DOSE
EFFECT

REFERENCE
N/R
N/R N/R N/R

REVIEWS:
ORGANIZATION STANDARD
REFERENCE

American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value time-weighted average 0.1 ppm DTLVS* TLV/BEI,2007
TOXICOLOGY REVIEW
HBTME* ,353,2007

STANDARDS AND REGULATIONS:
ORGANIZATION STANDARD
REFERENCE

Mine Safety and Health Administration (MSHA) STANDARD - air time-weighted average 0.1 ppm (0.5 mg/m³) DTLVS* 3,233,1971
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (General Industry) 8 hour time-weighted average 0.1 ppm (0.5 mg/m³) CFRGBR 29,1910.1000,1994
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Construction) 8 hour time-weighted average 0.1 ppm (0.5 mg/m³) CFRGBR 29,1926.55,1994
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Shipyards) 8 hour time-weighted average 0.1 ppm (0.5 mg/m³) CFRGBR 29,1915.1000,1993
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Federal Contractors) 8 hour time-weighted average 0.1 ppm (0.5 mg/m³) CFRGBR 41,50-204.50,1994
Occupational Exposure Limit - AUSTRALIA time-weighted average 0.1 ppm (0.51 mg/m³), JUL2008
Occupational Exposure Limit - BELGIUM time-weighted average 0.1 ppm (0.52 mg/m³), MAR2002
Occupational Exposure Limit - DENMARK time-weighted average 0.05 ppm (0.25 mg/m³), OCT 2002
Occupational Exposure Limit - DENMARK time-weighted average 0.5 mg(Sb)/m³, OCT 2002
Occupational Exposure Limit - FRANCE VME 0.1 ppm (0.5 mg/m³), FEB2006
Occupational Exposure Limit - HUNGARY time-weighted average 0.5 mg/m³, short term exposure limit 2 mg/m³, SEP2000
Occupational Exposure Limit - KOREA time-weighted average 0.1 ppm (0.5 mg/m³), 2006
Occupational Exposure Limit - MEXICO time-weighted average 0.1 ppm (0.5 mg/m³);
short term exposure limit 0.3 ppm (1.5 mg/m³), 2004
Occupational Exposure Limit - MEXICO time-weighted average 0.5 mg(Sb)/m³, 2004
Occupational Exposure Limit - THE NETHERLANDS MAC-TGG 0.5 mg(Sb)/m³, 2003
Occupational Exposure Limit - THE NETHERLANDS MAC-TGG 0.5 mg/m³, 2003
Occupational Exposure Limit - NEW ZEALAND time-weighted average 0.1 ppm (0.51 mg/m³), JAN2002
Occupational Exposure Limit - NORWAY time-weighted average 0.05 ppm (0.25 mg/m³), JAN1999
Occupational Exposure Limit - POLAND MAC(time-weighted average) 0.2 mg/m³, MAC(short term exposure limit) 1.5 mg/m³, JAN1999
Occupational Exposure Limit - RUSSIA time-weighted average 0.2 mg(Sb)/m³, short term exposure limit 0.5 mg(Sb)/m³, JUN2003
Occupational Exposure Limit - SWEDEN time-weighted average 0.05 ppm (0.3 mg/m³), JUN2005
Occupational Exposure Limit - SWITZERLAND MAK- week 0.1 ppm (0.5 mg/m³);
KZG- week 0.1 ppm (0.5 mg/m³),DEC2006
Occupational Exposure Limit - UNITED KINGDOM time-weighted average 0.5 mg(Sb)/m³, 2005

NIOSH DOCUMENTATION AND SURVEILLANCE:
ORGANIZATION STANDARD or SURVEY
REFERENCE

National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO STIBINE-air 10 hour time-weighted average 0.1 ppm NIOSH* DHHS #92-100,1992
National Occupational Exposure Survey 1983 National Occupational Exposure Survey 1983: Hazard Code: X5764;
Number of Industries 1;
Total Number of Facilities 23;
Number of Occupations 1;
Total Number of Employees Exposed 23

STATUS IN FEDERAL AGENCIES:
ORGANIZATION
REFERENCE

NIOSH Analytical Method, 1994: Stibine, 6008

REFERENCES:
CODEN
REFERENCE

28ZLA8 "Toxicity of Industrial Metals," Browning, E., London, Butterworths, 1961
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996
HBTME*

JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU.
NIOSH* National Institute of Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda.
VCVN5* "Vrednie chemichescie veshestva. Neorganicheskie soedinenia elementov V-VII groopp" (Hazardous substances. Inornanic substances containing V-VII group elements), Bandman A.L. et al., Chimia, 1989.

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SYNONYMS:
Antimonwasserstoffes (German) Antimony hydride Antimony trihydride	Antymonowodor (Polish) Hydrogen antimonide Stibine (ACGIH:OSHA)

SKIN AND EYE IRRITATION DATA AND REFERENCES:
ROUTE/ ORGANISM	DOSE	EFFECT	REFERENCE
N/R	N/R	N/R	N/R

MUTATION DATA AND REFERENCES:
SYSTEM TEST	ROUTE/ ORGANISM/ TISSUE	DOSE	REFERENCE
N/R	N/R	N/R	N/R

REPRODUCTIVE EFFECTS DATA AND REFERENCES:
ROUTE/ ORGANISM	DOSE	EFFECT	REFERENCE
N/R	N/R	N/R	N/R

TUMORIGENIC DATA AND REFERENCES:
ROUTE/ ORGANISM	DOSE	EFFECT	REFERENCE
N/R	N/R	N/R	N/R

ACUTE TOXICITY DATA AND REFERENCES:
ROUTE/ ORGANISM	DOSE	EFFECT	REFERENCE
inhalation cat	lowest published lethal concentration: 40 ppm/1 hour	Lung, Thorax, or Respiration: Acute pulmonary edema	JIHTAB 28,167,1946
inhalation cat	lowest published lethal concentration: 500 mg/m³/20 minute	Lung, Thorax, or Respiration: Acute pulmonary edema	VCVN5* -,105,1993
inhalation dog	lowest published lethal concentration: 40 ppm/1 hour	Lung, Thorax, or Respiration: Acute pulmonary edema	JIHTAB 28,167,1946
inhalation dog	lowest published lethal concentration: 500 mg/m³/20 minute	Lung, Thorax, or Respiration: Acute pulmonary edema	VCVN5* -,105,1993
inhalation dog	lowest published lethal concentration: 200 mg/m³/1 hour	Kidney, Ureter, and Bladder: Hematuria Blood: Other hemolysis with or without anemia	VCVN5* -,105,1993
inhalation guinea pig	lowest published lethal concentration: 92 ppm/1 hour	Kidney, Ureter, and Bladder: Changes in tubules (including acute renal failure, acute tubular necrosis)	28ZLA8 -,30,1961
inhalation guinea pig	lowest published lethal concentration: 500 mg/m³/20 minute	Lung, Thorax, or Respiration: Acute pulmonary edema	VCVN5* -,105,1993
inhalation mammal (species unspecified)	lowest published lethal concentration: 1 pph	N/R	VCVN5* -,105,1993
inhalation mouse	lowest published lethal concentration: 100 ppm/1 hour	N/R	28ZLA8 -,30,1961
inhalation mouse	lowest published lethal concentration: 500 mg/m³/20 minute	Lung, Thorax, or Respiration: Acute pulmonary edema	VCVN5* -,105,1993
inhalation rabbit	lowest published lethal concentration: 500 mg/m³/20 minute	Lung, Thorax, or Respiration: Acute pulmonary edema	VCVN5* -,105,1993

OTHER MULTIPLE DOSE DATA AND REFERENCES:
ROUTE/ ORGANISM	DOSE	EFFECT	REFERENCE
N/R	N/R	N/R	N/R

REVIEWS:
ORGANIZATION	STANDARD	REFERENCE
American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value	time-weighted average 0.1 ppm	DTLVS* TLV/BEI,2007
TOXICOLOGY REVIEW		HBTME* ,353,2007

STANDARDS AND REGULATIONS:
ORGANIZATION	STANDARD	REFERENCE
Mine Safety and Health Administration (MSHA) STANDARD - air	time-weighted average 0.1 ppm (0.5 mg/m³)	DTLVS* 3,233,1971
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (General Industry)	8 hour time-weighted average 0.1 ppm (0.5 mg/m³)	CFRGBR 29,1910.1000,1994
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Construction)	8 hour time-weighted average 0.1 ppm (0.5 mg/m³)	CFRGBR 29,1926.55,1994
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Shipyards)	8 hour time-weighted average 0.1 ppm (0.5 mg/m³)	CFRGBR 29,1915.1000,1993
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (Federal Contractors)	8 hour time-weighted average 0.1 ppm (0.5 mg/m³)	CFRGBR 41,50-204.50,1994
Occupational Exposure Limit - AUSTRALIA	time-weighted average 0.1 ppm (0.51 mg/m³), JUL2008
Occupational Exposure Limit - BELGIUM	time-weighted average 0.1 ppm (0.52 mg/m³), MAR2002
Occupational Exposure Limit - DENMARK	time-weighted average 0.05 ppm (0.25 mg/m³), OCT 2002
Occupational Exposure Limit - DENMARK	time-weighted average 0.5 mg(Sb)/m³, OCT 2002
Occupational Exposure Limit - FRANCE	VME 0.1 ppm (0.5 mg/m³), FEB2006
Occupational Exposure Limit - HUNGARY	time-weighted average 0.5 mg/m³, short term exposure limit 2 mg/m³, SEP2000
Occupational Exposure Limit - KOREA	time-weighted average 0.1 ppm (0.5 mg/m³), 2006
Occupational Exposure Limit - MEXICO	time-weighted average 0.1 ppm (0.5 mg/m³); short term exposure limit 0.3 ppm (1.5 mg/m³), 2004
Occupational Exposure Limit - MEXICO	time-weighted average 0.5 mg(Sb)/m³, 2004
Occupational Exposure Limit - THE NETHERLANDS	MAC-TGG 0.5 mg(Sb)/m³, 2003
Occupational Exposure Limit - THE NETHERLANDS	MAC-TGG 0.5 mg/m³, 2003
Occupational Exposure Limit - NEW ZEALAND	time-weighted average 0.1 ppm (0.51 mg/m³), JAN2002
Occupational Exposure Limit - NORWAY	time-weighted average 0.05 ppm (0.25 mg/m³), JAN1999
Occupational Exposure Limit - POLAND	MAC(time-weighted average) 0.2 mg/m³, MAC(short term exposure limit) 1.5 mg/m³, JAN1999
Occupational Exposure Limit - RUSSIA	time-weighted average 0.2 mg(Sb)/m³, short term exposure limit 0.5 mg(Sb)/m³, JUN2003
Occupational Exposure Limit - SWEDEN	time-weighted average 0.05 ppm (0.3 mg/m³), JUN2005
Occupational Exposure Limit - SWITZERLAND	MAK- week 0.1 ppm (0.5 mg/m³); KZG- week 0.1 ppm (0.5 mg/m³),DEC2006
Occupational Exposure Limit - UNITED KINGDOM	time-weighted average 0.5 mg(Sb)/m³, 2005

NIOSH DOCUMENTATION AND SURVEILLANCE:
ORGANIZATION	STANDARD or SURVEY	REFERENCE
National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO STIBINE-air	10 hour time-weighted average 0.1 ppm	NIOSH* DHHS #92-100,1992
National Occupational Exposure Survey 1983	National Occupational Exposure Survey 1983: Hazard Code: X5764; Number of Industries 1; Total Number of Facilities 23; Number of Occupations 1; Total Number of Employees Exposed 23

STATUS IN FEDERAL AGENCIES:
ORGANIZATION	REFERENCE
NIOSH Analytical Method, 1994: Stibine, 6008

REFERENCES:
CODEN	REFERENCE
28ZLA8	"Toxicity of Industrial Metals," Browning, E., London, Butterworths, 1961
CFRGBR	Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402)
DTLVS*	The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996
HBTME*
JIHTAB	Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU.
NIOSH*	National Institute of Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda.
VCVN5*	"Vrednie chemichescie veshestva. Neorganicheskie soedinenia elementov V-VII groopp" (Hazardous substances. Inornanic substances containing V-VII group elements), Bandman A.L. et al., Chimia, 1989.