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Surface chemistry of dihydromyrcenol (2,6-dimethyl-7-octen-2-ol) with ozone on silanized glass, glass, and vinyl flooring tiles.

Authors
Ham-JE; Wells-JR
Source
Atmos Environ 2009 Aug; 43(26):4023-4032
NIOSHTIC No.
20035879
Abstract
The surface-phase reaction products of dihydromyrcenol (2,6-dimethyl-7-octen-2-ol) with ozone (O-3), air, or nitrogen (N-2) on silanized glass, glass and vinyl flooring tile were investigated using the recently published FACS (FLEC (Field and Laboratory Emission Cell) Automation and Control System). The FACS was used to deliver ozone (100 ppb), air, or N-2 to the surface at a specified flow rate (300 mL min(-1)) and relative humidity (50%) after application of a 2.0% dihydromyrcenol solution in methanol. Oxidation products were detected using the derivatization agents: O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA) and N,O-bis(trimethysilyl)trifluoroacetamide (BSTFA). The positively identified reaction products were glycolaldehyde, 2,6-dimethyl-5-heptenal, and glyoxal. The proposed oxidation products based on previously published VOC/O-3 reaction mechanisms were: 2,6-dimethyl-4-heptenal, 6-methyl-7-octen-2-one and the surface-specific reaction products: 6-methyl-6-hepten-2-one, 6-methyl-5-hepten-2-one, and 6-hydroxy-6-methylheptan-2-one. Though similar products were observed in gasphase dihydromyrcenol/O-3 reactions, the ratio, based on peak area, of the reaction products was different suggesting stabilization of larger molecular weight species by the surface. Emission profiles of these oxidation products over 72 h are also reported.
Keywords
Air-quality; Chemical-composition; Chemical-indicators; Chemical-properties; Chemical-reactions; Chemical-synthesis; Emission-sources; Exposure-assessment; Exposure-levels; Exposure-methods; Gases; Indoor-environmental-quality; Oxidative-processes; Quantitative-analysis; Sampling-methods; Statistical-analysis; Surface-properties; Author Keywords: Dihydromyrcenol; Ozone; Reaction products; Surface chemistry
Contact
Jason E. Ham, Exposure Assessment Branch, Health Effects Laboratory Division, National Institute for Occupational Safety and Health, 1095 Willowdale Road, Morgantown, WV 26505
CODEN
AENVEQ
CAS No.
10028-15-6
Publication Date
20090801
Document Type
Journal Article
Email Address
bvo2@cdc.gov
Fiscal Year
2009
NTIS Accession No.
NTIS Price
Issue of Publication
26
ISSN
1352-2310
NIOSH Division
HELD
Priority Area
Services
Source Name
Atmospheric Environment
State
WV
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