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Surface chemistry reactions of a-terpineol [(R)-2-(4-methyl-3-cyclohexenyl)isopropanol] with ozone and air on a glass and a vinyl tile.

Authors
Ham-JE; Wells-JR
Source
Indoor Air 2008 Oct; 18(5):394-407
NIOSHTIC No.
20034617
Abstract
The surface-phase reaction products of a-terpineol [(R)-2-(4-methyl-3- cyclohexenyl)isopropanol] with ozone (O3), air or nitrogen (N2) on both a glass and vinyl flooring tile were investigated using the recently published FLEC Automation and Control System (FACS). The FACS was used to deliver O3 (100 ppb), air or N2 to the surface at a specified flow rate (300 ml/min) and relative humidity (50%) after application of a 1.6% a-terpineol solution in methanol. Oxidation products were detected using the derivatization agents: O-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine and N,O-bis(trimethysilyl)trifluoroacetamide. The positively identified reaction products were glyoxal, methylglyoxal and 4-oxopentanal. The proposed oxidation products based on previously published VOC/O3 reaction mechanisms were: 4-methylcyclohex-3- en-1-one, 6-hydroxyhept-en-2-one, 3-(1-hydroxy-1-methylethyl)-6-methylcyclohex- 2-en-1-one) and one surface-enhanced reaction product: 5-(1-hydroxy-1- methylethyl)-2-methylcyclohex-2-en-1-one. Though similar products were observed in gas-phase a-terpineol/O3 reactions, the ratio of the reaction products were different suggesting stabilization of larger molecular weight species by the surface. Emission profiles of these oxidation products over 72 h are also reported. Volatile organic compounds (VOCs) can interact with indoor initiators [such as hydroxyl radicals (OH.), ozone and nitrate radicals (NO3.)] to form a number of oxygenated by-products in the gas-phase. However, when VOCs are applied to or are present on the surface, heterogeneous chemistry with indoor initiators can also occur. The surface can influence the reaction mechanism to produce new surface reaction products. The work, described here, shows the interaction of a-terpineol (major component of pine oil) with ozone and air on both glass and vinyl flooring. These results demonstrated emissions of oxygenated organic compounds as a result of reaction and that further investigations of this chemistry are required to accurately estimate indoor occupant exposures.
Keywords
Quantitative-analysis; Sampling-methods; Air-quality; Indoor-air-pollution; Indoor-environmental-quality; Chemical-binding; Chemical-deposition; Chemical-composition; Chemical-properties; Chemical-reactions; Chemical-synthesis; Exposure-assessment; Exposure-levels; Exposure-methods; Vinyl-esters; Vinyl-plastics; Organic-chemicals; Organic-compounds; Organic-vapors; Gases
Contact
Jason E. Ham, Exposure Assessment Branch, Health Effects Laboratory Division, National Institute for Occupational Safety and Health, 1095 Willowdale Road, Morgantown, WV 26505
CODEN
INAIE5
CAS No.
10028-15-6; 67-56-1; 107-22-2; 78-98-8
Publication Date
20081001
Document Type
Journal Article
Email Address
bvo2@cdc.gov
Fiscal Year
2009
NTIS Accession No.
NTIS Price
Issue of Publication
5
ISSN
0905-6947
NIOSH Division
HELD
Priority Area
Services
Source Name
Indoor Air
State
WV
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