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Optical-fiber-mounted porous silicon photonic crystals for sensing organic vapor breakthrough in activated carbon.

Authors
King-BH; Ruminski-AM; Snyder-JL; Sailor-MJ
Source
Adv Mater 2007 Dec; 19(24):4530-4534
NIOSHTIC No.
20033293
Abstract
Fiber-optic-based sensors have been applied to a variety of remote sensing problems: measurement of pressure, humidity, vapor-phase chemicals, and aqueous biomolecules are leading examples.[1-6] With a width of only a few tens to hundreds of microns, these sensors require little power to operate, are impervious to electrical interference, and can be multiplexed together into distributed sensor configurations.[2,4,5] Fiber sensors may be extrinsic or intrinsic, depending on how the measured parameter is optically transduced;[4] intrinsic sensors, like interferometric and Fabry-Perot cavity devices, leverage the fiber's inherent optical properties to transform a parameter such as mechanical stress into an optical signal.[3,7,8] Extrinsic sensors, such as bead-based arrays[1] and polymer caps,[6] immobilize an indicator or label on the distal end of the fiber, using only the light-carrying capability of the fiber to transduce the sensor signal. In this work, an extrinsic sensor for volatile organic compounds (VOCs) is created by adhering a 0.5 mm-diameter porous Si photonic crystal to an optical fiber. Remote sensing with such a device is demonstrated by detecting breakthrough of VOCs in an activated carbon filtration bed.
Keywords
Monitors; Monitoring-systems; Organic-chemicals; Organic-compounds; Organic-vapors; Aerosols
Contact
M. J. Sailor, Department of Chemistry and Biochemistry, University of California - San Diego, La Jolla, CA 92093 (USA)
CODEN
ADVMEW
Publication Date
20071201
Document Type
Journal Article
Email Address
msailor@ucsd.edu
Fiscal Year
2008
NTIS Accession No.
NTIS Price
Issue of Publication
24
ISSN
0935-9648
NIOSH Division
NPPTL
Priority Area
All Sectors
Source Name
Advanced Materials
State
PA
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