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Electrowinning of neodymium from a molten oxide-fluoride electrolyte.

Authors
Dysinger-DK; Murphy-JE
Source
Reno, NV: U.S. Department of the Interior, Bureau of Mines, RI 9504, 1994 Jan; :1-8
Link
NIOSHTIC No.
10012354
Abstract
Neodymium metal of 99.8 percent purity was prepared by electrolysis of Nd2O3 salts dissolved in a molten fluoride electrolyte. The metal was electrowon in a molten state at current efficiencies of 50 to 60 percent. Oxygen and carbon were the major impurities detected in the product. During operation of the small scale laboratory cell, a number of technical problems including anode effect, low oxide solubility in the electrolyte, high neodymium metal solubility, reactivity of the metal with the cell materials, and back reaction of the metal with the anode gases were encountered. Approaches to improve cell operation and prospects for commercial adoption of the electrolytic production of neodymium metal are discussed.
Keywords
Electrolytes; Fluorides; Electrolytic-cells; Electrolysis; Commercial-development; Rare-earth-metals; Electrowinning; Electrometallurgy; Neodymium
Publication Date
19940101
Document Type
Report of Investigations
Fiscal Year
1994
NTIS Accession No.
PB94-178126
NTIS Price
A03
Identifying No.
RI-9504
NIOSH Division
RERC
Source Name
Reno, NV: U.S. Department of the Interior, Bureau of Mines, RI 9504
State
NV
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