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Hexafluorobenzene and 1,3-difluorobenzene low-temperature calorimetric studies and chemical thermodynamic properties.

Authors
Messerly-JF; Finke-HL
Source
J Chem Thermodynamics 1970 Nov; 2(6):867-880
NIOSHTIC No.
10010487
Abstract
The low-temperature thermal properties of hexafluorobenzene and 1,3-difluorobenzene were measured by adiabatic calorimetry from 13 to 342 K and 11 to 355 K, respectively. The properties measured were heat capacities of solid and liquid, enthalpies of fusion, triple point temperature, and purity, and, in addition, for 1,3-difluorobenzene, the enthalpy and temperature of a solid-solid transition. From these results the following chemical thermodynamic functions were calculated for the condensed phases at selected temperature: Gibbs energy function, enthalpy function, enthalpy, entropy, and heat capacity. For 1,3-difluorobenzene the entropies in the ideal gas state were calculated at several temperatures, a revised vibrational assignment was made from Raman and infrared frequencies reported in the literature, and the chemical thermodynamic functions in the ideal gas state were calculated from 0 to 1500 K. Values of the Gibbs energy of formation and logarithm of equilibrium constant of formation for 1,3-difluorobenzene were also computed for the range 0 to 1500 K.
CODEN
JCTDAF
Publication Date
19701101
Document Type
OP; Journal Article
Fiscal Year
1971
NTIS Accession No.
NTIS Price
Identifying No.
OP 12-71
Issue of Publication
6
ISSN
0021-9614
NIOSH Division
BERC
Source Name
The Journal of Chemical Thermodynamics
State
OK
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