Recording coulometer for controlled-atmosphere reactions of metals in molten salts.
Henrie-TA; MacDonald-DJ; Raddatz-AE
Rev Sci Instrum 1977 Jul; 48(7):793-795
An apparatus was designed and constructed to continuously record mass transfer to or from a metal electrode immersed in a molten-salt electrolyte while a constant current is passed through it, thereby providing a direct measure of the electron-to-atom transfer ratio. Special features include provisions for use of vacuum or inert gas atmospheres and for successive removals and replacements of electrode specimens without disturbing the molten-salt electrolyte. The technique proved successful on electrolyses in the nacl-ticl2- tic3 molten-salt system.
OP; Journal Article
Review of Scientific Instruments