Skip directly to search Skip directly to A to Z list Skip directly to page options Skip directly to site content

NIOSHTIC-2 Publications Search

Search Results

Correlations of Basic Gel Permeation Chromatography Data and Their Applications to High-boiling Petroleum Fractions.

Authors
Hirsch-DE; Dooley-JE; Coleman-HJ
Source
NTIS: PB 231 982 :77 pages
Link
NIOSHTIC No.
10009238
Abstract
The Bureau of Mines, as a part of American Petroleum Institute research project 60, characterization of the heavy ends of petroleum, has made extensive use of gel permeation chromatography (gpc). Data developed in this study were used to develop several correlations that greatly expanded the usefulness of gpc and the data have been used as an aid in the interpretation of mass spectra (ms). Gpc retention volume data on pure compounds were used with molecular structure to develop correlations that can be used to accurately predict retention volumes, molecular volumes, densities, chain lengths, and ring numbers of many components of petroleum without resorting to further laboratory experimentation. Conversely, the correlation can be used to select or reject some compounds from several possible compounds that are indicated on the basis of ms analysis. The utility of these correlations in compound type characterization is demonstrated by showing their application to 330 deg to 550 deg c fractions from a low-sulfur and a high- sulfur crude oil.
Publication Date
19740101
Document Type
IH; Report of Investigations
Fiscal Year
1974
NTIS Accession No.
PB-231982
NTIS Price
A06
Identifying No.
RI 7875
NIOSH Division
BERC;
Source Name
NTIS: PB 231 982
TOP