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Recovery of Metal Values from Lead Smelter Matte by Chlorine-oxygen Leaching.

Authors
Pool-DL; Scheiner-BJ; Hill-SD
Source
MISSING :19 pages
Link
NIOSHTIC No.
10006331
Abstract
To increase metal recoveries and to minimize pollution by improved extraction technology, the Bureau of Mines investigated a hydrometallurgical technique to recover copper, lead, nickel, and cobalt from lead smelter mattes. The metals were converted from insoluble sulfides to soluble chlorides using a hcl-cl2-o2 leaching system. Parameters studied in a 50-gallon, glass-lined reactor were the ratio of hydrochloric acid to chlorine, chlorine consumption per pound of matte, oxygen reaction pressure, and temperature. The matte material used contained, in percent, 19.7 Cu, 52 pb, 2.9 Ni, 1.5 Fe, 0.38 Co, 0.19 As, 0.41 Zn, and 0.12 Cd. Extraction of cu, pb, ni, CO, and cd ranged from 92 to 98 pct, with concomitant extractions of fe and as of < 0.1 pct. The cu and pb were recovered as electrowon metals, while the ni, CO, and cd were recovered as mixed hydroxides.
Publication Date
19820101
Document Type
IH; Report of Investigations
Fiscal Year
1982
NTIS Accession No.
NTIS Price
Identifying No.
RI 8615
NIOSH Division
RERC;
Source Name
MISSING
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