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The vapor-liquid equilibria of the aluminum chloride-titanium tetrachloride system.

Authors
Ko-HC; Landsberg-A
Source
Metall Trans B 1986 Sep; 17(3):609-610
NIOSHTIC No.
10005431
Abstract
As part of an overall investigation of the possibility of using domestic clay to produce aluminum via an energy saving chloride process, the Bureau of Mines has determined vapor-liquid equilibria for the system aluminum chloride-titanium tetrachloride. The system was studied over the entire composition range and at temperatures of 187 deg. to 217 deg. C in sealed vessels such that the total pressures were not known. Results indicate two azeotropes cf approximately 20 and 95 wt pct aluminum chloride. These findings suggest difficulties in distillation separation of these two products of clay chlorination.
Keywords
Metallurgical-processes; Mineral-processing; Chemical-reactions; Metal-compounds; Metallic-compounds; Aluminum-compounds
CODEN
MTTBCR
CAS No.
7429-90-5
Publication Date
19860901
Document Type
OP; Journal Article
Fiscal Year
1986
NTIS Accession No.
NTIS Price
Identifying No.
OP 160-86
Issue of Publication
3
ISSN
0360-2141
NIOSH Division
ALRC
Source Name
Metallurgical Transactions. B. Process Metallurgy
State
OR
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