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Ion chromatography of sulfur dioxide, sulfate ion, and dithionate ion in aqueous mineral leachates.

Authors
Petrie-LM; Jakel-EM; Brandvig-RL; Kroening-JG
Source
Anal Chem 1993 Apr; 65(7):952-955
NIOSHTIC No.
10004158
Abstract
We have described sample preparation and ion chromatography procedures that permit rapid, low-level, accurate measurement of S(IV) as SO3(2), SO4(2), and S2O6(2-) in aqueous mineral leachates. By using a pH 2.44 buffered diluent containing formaldehyde, Mn2+-catalyzed oxidation of S(IV) to SO4(2-) was prevented. These methods are applicable to a wide range of aqueous samples from the food, manufacturing, and environmental sectors, particularly when Mn2+, Fe3+, and other metal catalysts are present in the samples. The IC method for S206(2-) may be useful for environmental studies of SO2 reactivity since partial oxidation of SO2 can form SO3- radical which dimerizes to form S206(2-). It is important to remember these methods use standard commercial instrumentation, columns, and eluents.
Keywords
Analytical-chemistry; Analytical-processes; Sample-preparation; Mineral-processing; Sulfur-compounds
CODEN
ANCHAM
Publication Date
19930401
Document Type
Journal Article
Fiscal Year
1993
NTIS Accession No.
NTIS Price
Identifying No.
OP 100-93
Issue of Publication
7
ISSN
0003-2700
NIOSH Division
TCRC
Source Name
Analytical Chemistry
State
MN
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