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Analysis of dust and surface swab samples for octachlorodibenzo-p- dioxin and heptachlorodibenzo-p-dioxins by fused silica capillary GC with EC detection.

Authors
Korfmacher-WA; Rushing-LG; Nestorick-DM; Thompson-HC Jr.; Mitchum-RK; Kominsky-JR
Source
HRC & CC, J High Resolut Chromatogr Chromatogr Commun 1985 Jan; 8(1):12-19
NIOSHTIC No.
00155838
Abstract
A fused silica capillary gas chromatographic method for the analysis of octachlorodibenzo-p-dioxin (3268879) (OCDD) and heptachlorodibenzo-p-dioxin (35822469) (HpCDD) in dust and surface swab samples was tested. Swab samples were collected from a contaminated surface area and samples were extracted with hexane. The extracted samples were analyzed by gas chromatography equipped with electron capture detection system (GC/ECD). Dust samples were collected from horizontal surfaces made into a composite sample containing 30 to 40 grams of dust. Dust samples were extracted with benzene (71432). The sample extracts were subjected to a chemical purification procedure and subjected to high pressure liquid chromatography (HPLC). The purified samples were analyzed by GC/ECD. Samples were well separated by GC and ECD provided identification of OCDD and HpCDD. HPLC cleanup was capable of separating most of the polychlorinated biphenyls and other compounds from the HpCDD and OCDD. Recovery was in the range of 61 to 90 percent. The detection limit of the GC/ECD procedure was 0.5 picogram of OCDD. The detection limit was dependent on the sample matrix. The authors conclude that the GC/ECD procedure is reasonably accurate for analysis of swab and dust samples for the content of polychlorinated biphenyls.
Keywords
Sampling-methods; Materials-testing; Dust-exposure; Chromatographic-analysis; Detectors; Equipment-design; Qualitative-analysis; Air-sampling; Laboratory-techniques; Analytical-methods
CODEN
HCJCDB
CAS No.
3268-87-9; 35822-46-9; 71-43-2
Publication Date
19850101
Document Type
Journal Article
Fiscal Year
1985
NTIS Accession No.
NTIS Price
Issue of Publication
1
ISSN
0344-7138
Source Name
Journal of High Resolution Chromatography & Chromatography Communications: HRC & CC
State
OH
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