International Chemical Safety Cards

ESFENVALERATE ICSC: 1516
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
(S)-alpha-Cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl)-3-methylbutyrate
(S)-(R*,R*)-Cyano (3-phenoxyphenyl) methyl-4-chloro-alpha-(1-methylethyl) benzene acetate
(S-(R*,R*))-Benzeneacetic acid, 4-chloro-alpha-(1-methylethyl)-, cyano (3-phenoxyphenyl)methyl ester
(S)-alpha-Cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl)isovalerate
S-Fenvalerate
C25H22ClNO3
Molecular mass: 419.9
6 Harmful - Stow Away from Foodstuffs placard 6 Poison placard ICSC #    1516
CAS #     66230-04-4
RTECS # CY1576367
UN #        3349
EC #         650-033-00-5
April 23, 2004 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide .
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST!

 •INHALATION Cough. Sore throat. Dizziness. Headache. Nausea.
Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety goggles or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Salivation. Nausea. Vomiting. Headache. Dizziness. Tremors. Weakness. Convulsions.
Do not eat, drink, or smoke during work. Wash hands before eating.
Give a slurry of activated charcoal in water to drink. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. Personal protection: P3 filter respirator for toxic particles.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
T symbol
N symbol
R: 23/25-43-50/53
S: 1/2-24-36/37/39-45-60-61
UN Hazard Class: 6.1
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1516 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

ESFENVALERATE ICSC: 1516
I

M

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T

A

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D

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A
PHYSICAL STATE; APPEARANCE:
COLOURLESS TO WHITE CRYSTALS .

PHYSICAL DANGERS:


CHEMICAL DANGERS:


OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion .

INHALATION RISK:
Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is mildly irritating to the eyes , is irritating to the skin and the respiratory tract . The substance may cause effects on the nervous system .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization.
PHYSICAL
PROPERTIES
Melting point: 59-60C
Density: 1.2
g/cm
Solubility in water: none
Vapour pressure, Pa at 20C:
negligible
Flash point: 256C
Octanol/water partition coefficient as log Pow: 6.2
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
N O T E S
Carrier solvents used in commercial formulations may change physical and toxicological properties. If the substance is formulated with solvents also consult the ICSCs of these materials. Do NOT take working clothes home. The technical product is a brown to yellow liquid, with a melting point between 43-54C and a boiling point between 151-167C. See ICSC 0273 Fenvalerate. Card has been partly updated in April 2005. See section EU classification.
Transport Emergency Card: TEC (R)-61GT7-III
.
ADDITIONAL INFORMATION


ICSC: 1516 ESFENVALERATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.