International Chemical Safety Cards

DIPROPYL KETONE ICSC: 1414
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Heptan-4-one
Butyrone
C7H14O / (CH3CH2CH2)2CO
Molecular mass: 114.2
3 Flammable Liquid placard ICSC #    1414
CAS #     123-19-3
RTECS # MJ5600000
UN #        2710
EC #         606-027-00-X
May 03, 2002 Validated
Pi, Study (1st batch of chemical part)
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Flammable.
NO open flames, NO sparks, and NO smoking.
Alcohol-resistant foam, dry powder, carbon dioxide.
EXPLOSION Above 49C explosive vapour/air mixtures may be formed.
Above 49C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT GENERATION OF MISTS!

 •INHALATION Cough. Sore throat. Drowsiness. Dullness. Headache.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness. Dry skin.
Protective gloves.
Rinse skin with plenty of water or shower.
 •EYES Redness.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Nausea. Vomiting. Diarrhoea. Dizziness. Drowsiness.
Do not eat, drink, or smoke during work.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Remove all ignition sources. Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours.)
Fireproof. Separated from strong oxidants. Well closed.

Xn symbol
R: 10-20
S: 2-24/25
UN Hazard Class: 3
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1414 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

DIPROPYL KETONE ICSC: 1414
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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
Reacts with oxidants , bases and reducing agents .

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 50 ppm as TWA (ACGIH 2000).
OSHA PEL: none
NIOSH REL: TWA 50 ppm (235 mg/m3)
NIOSH IDLH: N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

INHALATION RISK:
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20C; on spraying or dispersing, however, much faster.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is mildly irritating to the eyes and the skin . The vapour is irritating to the respiratory tract . Exposure at high levels may result in lowering of consciousness.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The liquid defats the skin.
PHYSICAL
PROPERTIES
Boiling point: 144-146C
Melting point: -33C
Relative density (water = 1): 0.8
Solubility in water, g/100 ml at 20C: very poor
Vapour pressure, kPa at 20C: 0.7
Relative vapour density (air = 1): 3.9
Relative density of the vapour/air-mixture at 20C (air = 1): 1.01
Flash point: 49C
Auto-ignition temperature: 430C
Explosive limits, vol% in air: see Notes
ENVIRONMENTAL
DATA

N O T E S
Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61C.
NFPA Code: H2; F2; R0;

Transport Emergency Card: TEC (R)-30GF1-III
ADDITIONAL INFORMATION


ICSC: 1414 DIPROPYL KETONE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.