International Chemical Safety Cards

FENSULFOTHION ICSC: 1406
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
O,O-Diethyl O-(p-(methylsulfinyl)phenyl) phosphorothioate
O,O-Diethyl O-p-(methylsulfinyl)phenyl thiophosphate
C11H17O4PS2
Molecular mass: 308.36
6 Poison placard Marine Pollutant placard ICSC #    1406
CAS #     115-90-2
RTECS # TF3850000
UN #        3018
EC #         015-090-00-7
October 17, 2001 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION


EXPOSURE
AVOID ALL CONTACT!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Pupillary constriction, muscle cramp, excessive salivation. Sweating. Nausea. Laboured breathing. Dizziness. Convulsions. Unconsciousness.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
 •SKIN EASILY ABSORBED! (See Inhalation).
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
 •EYES
Face shield or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal cramps. Diarrhoea. Vomiting. (Further see Inhalation).
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment. Personal protection: chemical protection suit including self-contained breathing apparatus.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Well closed.
Do not transport with food and feedstuffs.
Marine pollutant.
T+ symbol
N symbol
R: 27/28-50/53
S: 1/2-23-28-36/37-45-60-61
UN Hazard Class: 6.1
UN Packing Group: I
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1406 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

FENSULFOTHION ICSC: 1406
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PHYSICAL STATE; APPEARANCE:
OILY, YELLOW OR BROWN LIQUID

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes including phosphorous oxides and sulfur oxides .

OCCUPATIONAL EXPOSURE LIMITS:
OSHA PEL: none
NIOSH REL: TWA 0.1 mg/m3
NIOSH IDLH: N.D. See: IDLH INDEX
TLV: 0.01 mg/m as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued; (ACGIH 2005).
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the nervous system , resulting in convulsions and respiratory failure . Cholinesterase inhibitor. Exposure above the OEL may result in death. The effects may be delayed. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Cholinesterase inhibitor; cumulative effect is possible: see acute hazards/symptoms.
PHYSICAL
PROPERTIES
Boiling point at 0.0013 kPa: 138-141 C
Relative density (water = 1): 1.202
Solubility in water, g/100 ml at 25C: 0.15
Vapour pressure, Pa at 25C: 0.0067
Octanol/water partition coefficient as log Pow: 2.23
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is toxic to aquatic organisms. This substance may be hazardous in the environment; special attention should be given to birds and honey bees. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
N O T E S
Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. Card has been partly updated in April and October 2005. See section Occupational Exposure Limits.
Transport Emergency Card: TEC (R)-61GT6-I
ADDITIONAL INFORMATION


ICSC: 1406 FENSULFOTHION
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.