International Chemical Safety Cards

GASOLINE ICSC: 1400
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Benzin
3 Flammable Liquid placard Marine Pollutant placard ICSC #    1400
CAS #     86290-81-5
RTECS # DE3550000
UN #        1203
EC #         649-378-00-4
October 18, 2001 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Highly flammable.
NO open flames, NO sparks, and NO smoking.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Vapour/air mixtures are explosive.
Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding).
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


 •INHALATION Confusion. Cough. Dizziness. Drowsiness. Dullness. Headache.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN MAY BE ABSORBED! Dry skin. Redness.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety spectacles or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Nausea. Vomiting. (See Inhalation).
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Remove all ignition sources. Cover the spilled material with dry earth, sand or non-combustible material. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Personal protection: self-contained breathing apparatus.
Fireproof.

Marine pollutant.
Note: H, P
T symbol
R: 45-65
S: 53-45
UN Hazard Class: 3
UN Packing Group: I
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1400 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

GASOLINE ICSC: 1400
I

M

P

O

R

T

A

N

T


D

A

T

A
PHYSICAL STATE; APPEARANCE:
MOBILE LIQUID

PHYSICAL DANGERS:
The vapour is heavier than air and may travel along the ground; distant ignition possible. The vapour mixes well with air, explosive mixtures are easily formed. As a result of flow, agitation, etc., electrostatic charges can be generated.

CHEMICAL DANGERS:


OCCUPATIONAL EXPOSURE LIMITS:
TLV: 300 ppm as TWA, 500 ppm as STEL; A3 (confirmed animal carcinogen with unknown relevance to humans); (ACGIH 2004).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

INHALATION RISK:
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The liquid defats the skin. The substance may have effects on the central nervous system and liver . This substance is possibly carcinogenic to humans.
PHYSICAL
PROPERTIES
Boiling point: 20-200C
Relative density (water = 1): 0.70 - 0.80
Solubility in water, g/100 ml:
none
Relative vapour density (air = 1): 3 - 4
Flash point: <-21C
Auto-ignition temperature: about 250C
Explosive limits, vol% in air: 1.3-7.1
Octanol/water partition coefficient as log Pow: 2-7
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is harmful to aquatic organisms.
N O T E S
Depending on the degree of exposure, periodic medical examination is suggested. The product may contain additives which may alter the health and environmental effects.Card has been partly updated in April 2005. See section Physical properties.
NFPA Code: H1; F3; R0;
Transport Emergency Card: TEC (R)-30S1203
ADDITIONAL INFORMATION


ICSC: 1400 GASOLINE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.