International Chemical Safety Cards

TRIPHENYLAMINE ICSC: 1366
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
N,N-Diphenylbenzenamine
N,N-Diphenylaniline
C18H15N / (C6H5)3N
Molecular mass: 245.3
ICSC #    1366
CAS #     603-34-9
RTECS # YK2680000
April 20, 2005 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.

EXPOSURE
PREVENT DISPERSION OF DUST!

 •INHALATION
Ventilation.
Fresh air, rest.
 •SKIN Redness.
Protective gloves.
Rinse and then wash skin with water and soap.
 •EYES Redness.
Safety goggles .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work.
Rinse mouth.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting.
Separated from acids, strong oxidants, and halogens .

SEE IMPORTANT INFORMATION ON BACK
ICSC: 1366 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

TRIPHENYLAMINE ICSC: 1366
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PHYSICAL STATE; APPEARANCE:
COLOURLESS TO WHITE POWDER , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes including nitrogen oxides . The solution in water is a weak base. Reacts with acids , strong oxidants and halogens .

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 5 mg/m as TWA; (ACGIH 2005).
MAK not established.
OSHA PEL: none
NIOSH REL: TWA 5 mg/m3
NIOSH IDLH: N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by ingestion.

INHALATION RISK:
A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is mildly irritating to the eyes and the skin .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Boiling point: 365C
Melting point: 126.5C
Density: 0.77
g/cm
Solubility in water:
very poor
Flash point: 180C o.c.
Octanol/water partition coefficient as log Pow: 5.74
ENVIRONMENTAL
DATA

N O T E S
Environmental effects from the substance have not been investigated.
ADDITIONAL INFORMATION


ICSC: 1366 TRIPHENYLAMINE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.