International Chemical Safety Cards

IMAZALIL ICSC: 1303
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Allyl 1-(2,4-dichlorophenyl)-2-imidazol-1-ylethyl ether
1-(2-(2,4-Dichlorophenyl)-2-(2-propenyloxy)ethyl)-1H-imidazole
Enilconazole
C14H14Cl2N2O
Molecular mass: 297.2
ICSC #    1303
CAS #     35554-44-0
RTECS # NI4776000
EC #         613-042-00-5
November 25, 1998 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION


EXPOSURE


 •INHALATION

Fresh air, rest.
 •SKIN
Protective gloves.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
 •EYES Redness. Pain.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Nausea.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. (Extra personal protection: chemical protection suit including self-contained breathing apparatus).
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
Xn symbol
N symbol
R: 20/22-41-50/53
S: 2-26-39-60-61
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1303 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

IMAZALIL ICSC: 1303
I

M

P

O

R

T

A

N

T


D

A

T

A
PHYSICAL STATE; APPEARANCE:
LIGHT YELLOW TO BROWN CRYSTALLINE MASS (SOLIDIFIED OIL).

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on distillation or on burning producing toxic fumes of nitrogen oxides and chloride.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates severely the eyes.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the liver , resulting in impaired functions and tissue lesions.
PHYSICAL
PROPERTIES
Boiling point: (estimated) 319-347°C
Melting point: 50°C
Relative density (water = 1): 1.2
Solubility in water, g/100 ml at 20°C: 0.14
Vapour pressure, Pa at 20°C: negligible
Flash point: 192°C
Octanol/water partition coefficient as log Pow: 4.56
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.
N O T E S
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Bromazil, Deccozil, Fecundal, Florasan, Freshgard, Fungaflor, Fungazil, Imaverol, Impala, Magnate, Sanazil are trade names.
ADDITIONAL INFORMATION


ICSC: 1303 IMAZALIL
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.