International Chemical Safety Cards

DIAMMONIUM HYDROGEN ARSENATE ICSC: 1207
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Arsenic acid, diammonium salt
Ammonium arsenate
(NH4)2HAsO4
Molecular mass: 176.0
6 Poison placard Marine Pollutant placard ICSC #    1207
CAS #     7784-44-3
RTECS # CG0850000
UN #        1546
EC #         033-005-00-1
October 18, 1999 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! AVOID EXPOSURE OF (PREGNANT) WOMEN!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Cough. Sore throat. Headache. Laboured breathing. Weakness. See Ingestion.
Closed system and ventilation.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
 •EYES Redness. Pain.
Face shield or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Diarrhoea. Vomiting. Burning sensation in the throat and chest. Shock or collapse.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Vacuum spilled material. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. Chemical protection suit including self-contained breathing apparatus.
Separated from acids, food and feedstuffs . Well closed.
Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.
Marine pollutant.
Note: A, E
T symbol
N symbol
R: 45-23/25-50/53
S: 53-45-60-61
UN Hazard Class: 6.1
UN Packing Group: II
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1207 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

DIAMMONIUM HYDROGEN ARSENATE ICSC: 1207
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A

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A
PHYSICAL STATE; APPEARANCE:
COLOURLESS CRYSTALS , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating producing toxic fumes including ammonia , nitrogen oxides and arsenic fumes . Reacts with bases to produce ammonia . Attacks many metals in presence of water such as iron, aluminium and zinc, releasing toxic fumes of arsine (see ICSC 0222).

OCCUPATIONAL EXPOSURE LIMITS:
TLV: (as As) 0.01 mg/m³; A1 (confirmed human carcinogen); BEI issued; (ACGIH 2004).
MAK:
Carcinogen category: 1; Germ cell mutagen group: 3A;
(DFG 2004).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . The substance may cause effects on the gastrointestinal tract , central nervous system , cardiovascular system and kidneys , resulting in severe gastroenteritis, loss of fluids and electrolytes, shock , cardiac disorders and kidney impairment . Exposure above the OEL may result in death. The effects may be delayed.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the skin, mucous membranes, peripheral nervous system , bone marrow and liver , resulting in pigmentation disorders, perforation of nasal septum, neuropathy and liver impairment . This substance is carcinogenic to humans. Animal tests show that this substance possibly causes malformations in human babies.
PHYSICAL
PROPERTIES
Density: 2.0
g/cm³
Solubility in water: good
ENVIRONMENTAL
DATA
Environmental Hazard placard This substance may be hazardous in the environment; special attention should be given to ground water contamination,aquatic organisms and soil organisms. It is strongly advised that this substance does not enter the environment.
N O T E S
Depending on the degree of exposure, periodic medical examination is suggested. Do NOT take working clothes home. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response.October 2005: see section Effects of long-term or repeated exposure.
Transport Emergency Card: TEC (R)-61GT5-II
ADDITIONAL INFORMATION


ICSC: 1207 DIAMMONIUM HYDROGEN ARSENATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.