International Chemical Safety Cards

N-PHENYL-1-NAPHTHYLAMINE ICSC: 1113
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
N-(1-Naphthyl)aniline
N-Phenyl-alpha-naphthylamine
C16H13N / C10H7NHC6H5
Molecular mass: 219.30
ICSC #    1113
CAS #     90-30-2
RTECS # QM4500000
March 24, 1998 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
AVOID ALL CONTACT!

 •INHALATION Blue lips or finger nails. Blue skin. Confusion. Convulsions. Dizziness. Headache. Nausea. Unconsciousness.
Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN MAY BE ABSORBED!
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
 •EYES
Face shield.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION (See Inhalation).
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment.
Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.

SEE IMPORTANT INFORMATION ON BACK
ICSC: 1113 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

N-PHENYL-1-NAPHTHYLAMINE ICSC: 1113
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PHYSICAL STATE; APPEARANCE:
WHITE TO SLIGHT YELLOWISH CRYSTALS.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes including nitrogen oxides.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK: IIb (not established but data is available); sensitization of skin (Sh); (DFG 2009.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the blood , resulting in formation of methaemoglobin. The effects may be delayed. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization.
PHYSICAL
PROPERTIES
Melting point: 62-63C
Relative density (water = 1): 1.2
Solubility in water: none
Octanol/water partition coefficient as log Pow: 4.2
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. In the food chain important to humans, bioaccumulation takes place, specifically in fish.
N O T E S
Depending on the degree of exposure, periodic medical examination is indicated. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Card has been partially updated in November 2008: see Occupational Exposure Limits, Storage.
Card has been partially updated in April 2010: see Occupational Exposure Limits, Spillage Disposal.
ADDITIONAL INFORMATION


ICSC: 1113 N-PHENYL-1-NAPHTHYLAMINE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.