International Chemical Safety Cards

N-ISOPROPYL-N'-PHENYL-p-PHENYLENEDIAMINE ICSC: 1108
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
4-(Isopropylamino)diphenylamine
N-(1-Methylethyl)-N'-phenyl-1,4-benzenediamine
4-Anilino-N-isopropylaniline
C15H18N2
Molecular mass: 226.4
ICSC #    1108
CAS #     101-72-4
RTECS # ST2650000
EC #         612-136-00-3
March 23, 1999 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Water spray, powder.
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.

EXPOSURE
AVOID ALL CONTACT!

 •INHALATION
Ventilation (not if powder), local exhaust, or breathing protection.
Fresh air, rest.
 •SKIN Redness.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
 •EYES Redness. Pain.
Safety goggles, or face shield.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work.
Rinse mouth.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. Personal protection: chemical protection suit.
Well closed.
Do not transport with food and feedstuffs.
Xn symbol
N symbol
R: 22-43-50/53
S: 2-24-37-60-61
SEE IMPORTANT INFORMATION ON BACK
ICSC: 1108 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

N-ISOPROPYL-N'-PHENYL-p-PHENYLENEDIAMINE ICSC: 1108
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PHYSICAL STATE; APPEARANCE:
DARK GREY TO BLACK TO BLACK FLAKES

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes including nitrogen oxides.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes and the skin .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization.
PHYSICAL
PROPERTIES
Melting point: 72-76C
Density: 1.04
g/cm
Solubility in water:
none
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment.
N O T E S
Santoflex IP, Flexzone 3C, Nocrac 810NA, Elastozone 34, Nonox ZA are trade names. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION


ICSC: 1108 N-ISOPROPYL-N'-PHENYL-p-PHENYLENEDIAMINE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.