International Chemical Safety Cards

2,4,6-TRINITROTOLUENE ICSC: 0967
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
2-Methyl-1,3,5-trinitrobenzene
1-Methyl-2,4,6-trinitrobenzene
TNT
C7H5N3O6 / C6H2(CH3)(NO2)3
Molecular mass: 227.1
Explosive placard ICSC #    0967
CAS #     118-96-7
RTECS # XU0175000
UN #        0209
EC #         609-008-00-4
April 13, 2000 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Explosive. Many reactions may cause fire or explosion.
NO open flames, NO sparks, and NO smoking.
Water in large amounts. Do not attempt to extinguish large fire, evacuate area.
EXPLOSION Risk of fire and explosion upon rapid heating or strong shock.
Do NOT expose to friction or shock. Do not expose to heat and keep wet with at least 30% water.
In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.
EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Headache. Blue lips or finger nails. Blue skin. Cough. Sore throat. Laboured breathing. Vomiting. Abdominal cramps. Unconsciousness. Symptoms may be delayed (see Notes).
Local exhaust or breathing protection.
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
 •SKIN MAY BE ABSORBED! Redness. Pain. Yellowish staining. (Further see Inhalation).
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. Wear protective gloves when administering first aid.
 •EYES Redness. Pain.
Face shield or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION (Further see Inhalation).
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Wear protective gloves when inducing vomiting.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Wet spilled material before picking it up, do not attempt to sweep up dry material. Do NOT wash away into sewer. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. Chemical protection suit including self-contained breathing apparatus.
Fireproof. Separated from initiator explosives, food and feedstuffs, incompatible materials. See Chemical Dangers. Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.
E symbol
T symbol
N symbol
R: 2-23/24/25-33-51/53
S: 1/2-35-45-61
UN Hazard Class: 1.1D
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0967 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

2,4,6-TRINITROTOLUENE ICSC: 0967
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PHYSICAL STATE; APPEARANCE:
COLOURLESS TO YELLOW CRYSTALS

PHYSICAL DANGERS:


CHEMICAL DANGERS:
May explosively decompose on shock, friction, or concussion. Explodes on heating to 240°C. Upon heating, toxic fumes are formed. Reacts violently with many chemicals (seek expert help) causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 0.1 mg/m³; (skin); (ACGIH 2004).
MAK: skin absorption (H); sensitization of skin (Sh);
Carcinogen category: 2; Germ cell mutagen group: 3B
(DFG 2008).
OSHA PEL: TWA 1.5 mg/m3 skin
NIOSH REL: TWA 0.5 mg/m3 skin
NIOSH IDLH: 500 mg/m3 See: 118967


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . The substance may cause effects on the blood , resulting in hemolysis, formation of methaemoglobin. Exposure may result in death. The effects may be delayed (see Notes). Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the liver, blood and eyes , resulting in jaundice, anaemia, cataract.
PHYSICAL
PROPERTIES
Boiling point (decomposes): 240°C
Melting point: 80.1°C
Density: 1.65
g/cm³
Solubility in water, g/100 ml at 20°C: 0.013
Vapour pressure, Pa at 20°C: negligible
Relative vapour density (air = 1): 7.85
Octanol/water partition coefficient as log Pow: 1.60
Vapour pressure, Pa at 100°C: 14
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment because it persists in the environment.
N O T E S
Combustion in a confined space may turn into detonation. Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Do NOT take working clothes home. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response.
Transport Emergency Card: TEC (R)-10G1.1
NFPA Code: H 2; F 4; R 4;
Card has been partially updated in November 2008: see Occupational Exposure Limits,
ADDITIONAL INFORMATION


ICSC: 0967 2,4,6-TRINITROTOLUENE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.