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NICKEL CARBONATE

ICSC: 0927

Nickelous carbonate
Nickel(II) carbonate
NiCO3
Molecular mass: 118.7
ICSC #    0927
CAS #     3333-67-3
RTECS # QR6200000
UN #        3288
EC #         028-010-00-0
March 10, 2000 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION


EXPOSURE
AVOID ALL CONTACT!

 •INHALATION Cough.
Closed system and ventilation.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness. Pain.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
 •EYES Redness.
Safety goggles or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work.
Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P3 filter respirator for toxic particles. Do NOT let this chemical enter the environment.
Separated from food and feedstuffs . See Chemical Dangers.
Do not transport with food and feedstuffs.
Xn symbol
N symbol
R: 22-40-43-50/53
S: 2-22-36/37-60-61
UN Hazard Class: 6.1
UN Packing Group: III
ICSC: 0927 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

NICKEL CARBONATE

ICSC: 0927

I

M

P

O

R

T

A

N

T


D

A

T

A

PHYSICAL STATE; APPEARANCE:
LIGHT GREEN CRYSTALS

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating and on contact with acids producing carbon dioxide (see ICSC 0021). Reacts violently with aniline, hydrogen sulfide, flammable solvents, hydrazine and metal powders, especially zinc, aluminium and magnesium, causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 0.2 mg/m3 as TWA; A1 (confirmed human carcinogen); (ACGIH 2004).
MAK: sensitization of respiratory tract and skin (Sah);
Carcinogen category: 1;
(DFG 2004).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed .

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the skin .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization. Repeated or prolonged inhalation exposure may cause asthma. The substance may have effects on the lungs. This substance is carcinogenic to humans.

PHYSICAL
PROPERTIES

Decomposes below melting point
Density: 2.6g/cm3
Solubility in water:
none

ENVIRONMENTAL
DATA

The substance is harmful to aquatic organisms.

N O T E S

Temperature of decomposition unknown in literature. Do NOT take working clothes home. Anyone who has shown symptoms of asthma due to this substance should avoid all further contact with this substance. The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Card has been partly updated in April 2005. See section Occupational Exposure Limits.
Transport Emergency Card: TEC (R)-61GT5-III

ADDITIONAL INFORMATION



ICSC: 0927 NICKEL CARBONATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
 
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