International Chemical Safety Cards

LAMBDA-CYHALOTHRIN ICSC: 0859
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
alpha-Cyano-3-phenoxybenzyl 3-(2-chloro-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylate;
a 11 reaction mixture of the (Z)-(1R,3R), (S) ester and (Z)-(1S,3S), (R) ester
C23H19ClF3NO3
Molecular mass: 449.9
6 Harmful - Stow Away from Foodstuffs placard 6 Poison placard ICSC #    0859
CAS #     91465-08-6
RTECS # GZ1227780
UN #        2588
EC #         607-252-00-6
September 04, 1997 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.

Alcohol-resistant foam, dry sand, powder, carbon dioxide.
EXPLOSION Risk of fire and explosion if formulations contain flammable/explosive solvents.


EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Burning sensation. Convulsions. Cough. Laboured breathing. Shortness of breath. Sore throat.
Local exhaust, or breathing protection.
Fresh air, rest.
 •SKIN Redness. Pain.
Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety spectacles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Cough.
Do not eat, drink, or smoke during work. Wash hands before eating.
Do NOT induce vomiting. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. Personal protection: P3 filter respirator for toxic particles.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Cool. Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
T+ symbol
N symbol
R: 21-25-26-50/53
S: 1/2-28-36/37/39-38-45-60-61
UN Hazard Class: 6.1
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0859 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

LAMBDA-CYHALOTHRIN ICSC: 0859
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PHYSICAL STATE; APPEARANCE:
COLOURLESS TO BEIGE SOLID (TECHNICAL GRADE).

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes including nitrogen oxides hydrogen chloride and hydrogen fluoride .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of fine dust and mist and by ingestion.

INHALATION RISK:


EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . The substance may cause effects on the peripheral nervous system , resulting in convulsions, ataxia.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Decomposes below boiling point at 275C
Melting point: 49.2C
Relative density (water = 1): 1.3
Solubility in water:
none
Vapour pressure, Pa at 20C: <0.001
Octanol/water partition coefficient as log Pow: 7.0
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. The substance may be hazardous to the environment; special attention should be given to mammals and honey bees. The substance may cause long-term effects in the aquatic environment. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
N O T E S
Liquid formulation can be aspired into the lungs resulting in chemical pneumonitis, showing tremors and convultions. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. The recommendations on this Card also apply to cyhalothrin. Karate, Charge, Commodore, Excalibur, Hallmark, Icon, Matador, PP 321, Saber, and Sentinel are trade names. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
Transport Emergency Card: TEC (R)-61GT7-III
ADDITIONAL INFORMATION


ICSC: 0859 LAMBDA-CYHALOTHRIN
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.