International Chemical Safety Cards

ANTIMONY ICSC: 0775
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Antimony black
Antimony regulus
Stibium
Sb
Atomic mass: 121.8
6 Harmful - Stow Away from Foodstuffs placard 6 Poison placard ICSC #    0775
CAS #     7440-36-0
RTECS # CC4025000
UN #        2871
October 12, 2006 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible under specific conditions. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames. NO contact with oxidants, halogens, acid(s).
water spray, foam, powder, carbon dioxide
EXPLOSION Finely dispersed particles form explosive mixtures in air. Risk of fire and explosion on contact with .
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.

EXPOSURE
PREVENT DISPERSION OF DUST!

 •INHALATION Cough. (See Ingestion).
Local exhaust or breathing protection.
Fresh air, rest.
 •SKIN
Protective gloves.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety goggles, or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Vomiting. Diarrhoea.
Do not eat, drink, or smoke during work.
Rinse mouth. Refer for medical attention if you feel unwell.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting.
Separated from oxidants , acids, halogens , food and feedstuffs.
Do not transport with food and feedstuffs.
UN Hazard Class: 6.1
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0775 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

ANTIMONY ICSC: 0775
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PHYSICAL STATE; APPEARANCE:
SILVER-WHITE, LUSTROUS, HARD, BRITTLE LUMPS OR DARK GRAY POWDER

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
On combustion, forms toxic fumes (antimony oxides; see ICSC 0012). Reacts violently with oxidants, , causing fire and explosion hazard. On contact with acids may emit toxic gas (stibine; see ICSC 0776).

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 0.5 mg/m³ as TWA (ACGIH 2006).
MAK:
Carcinogen category: 2; Germ cell mutagen group: 3B
(DFG 2006).
OSHA PEL*: TWA 0.5 mg/m3 *Note: The PEL also applies to other antimony compounds (as Sb).
NIOSH REL*: TWA 0.5 mg/m3 *Note: The REL also applies to other antimony compounds (as Sb).
NIOSH IDLH: 50 mg/m3 (as Sb) See: 7440360


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol.

INHALATION RISK:
A harmful concentration of airborne particles can be reached quickly when dispersed.

EFFECTS OF SHORT-TERM EXPOSURE:
May cause mechanical irritation to the eyes.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis, especially when exposed to fumes. The substance may have effects on the lungs , resulting in pneumoconiosis.
PHYSICAL
PROPERTIES
Boiling point: 1635 °C
Melting point: 630 °C
Density: 6.7
g/cm³
Solubility in water: none
ENVIRONMENTAL
DATA

N O T E S
Other boiling points: 1325°C, 1440°C, 1587 °C, 1750°C. The recommendations on this card apply only to metallic antimony. See ICSC 0012 antimony trioxide, ICSC 1224 antimony trichloride, ICSC 0220 antimony pentafluoride and ICSC 0776 antimony trihydride.
Transport Emergency Card: TEC (R)-61GT5-III
ADDITIONAL INFORMATION


ICSC: 0775 ANTIMONY
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.