International Chemical Safety Cards

4-AMINOBIPHENYL ICSC: 0759
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
(1,1'-Biphenyl)-4-amine
p-Biphenylamine
p-Xenylamine
4-Aminodiphenyl
C12H11N / C6H5C6H4NH2
Molecular mass: 169.2
ICSC #    0759
CAS #     92-67-1
RTECS # DU8925000
EC #         612-072-00-6
August 04, 1997 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION


EXPOSURE
AVOID ALL CONTACT!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Dullness. Headache.
Closed system and ventilation.
Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
 •SKIN
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
 •EYES Redness.
Safety goggles, face shield, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work.
Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (Extra personal protection: complete protective clothing including self-contained breathing apparatus).
Separated from strong oxidants. Well closed.
Unbreakable packaging; put breakable packaging into closed unbreakable container.
Note: E
T symbol
R: 45-22
S: 53-45
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0759 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

4-AMINOBIPHENYL ICSC: 0759
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PHYSICAL STATE; APPEARANCE:
COLOURLESS SOLID IN VARIOUS FORMS , WITH CHARACTERISTIC ODOUR. TURNS PURPLE ON EXPOSURE TO AIR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
On combustion, forms toxic gases. The solution in water is a weak base. Reacts with strong oxidants.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: A1 (skin) (ACGIH 1996).
MAK: skin absorption (H);
Carcinogen category: 1
(DFG 2006).
OSHA PEL: 1910.1011 See Appendix B
NIOSH REL: Ca See Appendix A
NIOSH IDLH: Ca N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly by dispersing.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes. The substance may cause effects on the bladder , resulting in blood in urine.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
This substance is carcinogenic to humans.
PHYSICAL
PROPERTIES
Boiling point: 302C
Melting point: 53C
Relative density (water = 1): 1.2
Solubility in water, g/100 ml at 25C: 0.2
Flash point: 153C c.c.
Auto-ignition temperature: 450C
Octanol/water partition coefficient as log Pow: 2.8
ENVIRONMENTAL
DATA

N O T E S
Periodic medical examination is indicated. Special attention should be given to urine sediment and cytology. Do NOT take working clothes home.
Transport Emergency Card: TEC (R)-61G12b

NFPA Code: H2; F1; R0;
Card has been partially updated in August 2007: see Occupational Exposure Limits.
ADDITIONAL INFORMATION


ICSC: 0759 4-AMINOBIPHENYL
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.