International Chemical Safety Cards DIETHANOLAMINE ICSC: 0618 2,2'-Iminodiethanol DEA 2,2'-Dihydroxydiethylamine C4H11NO2 / (CH2CH2OH)2NH Molecular mass: 105.2 ICSC #    0618 CAS #     111-42-2 RTECS # KL2975000 EC #         603-071-00-1 October 10, 2002 Validated TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST! PREVENT GENERATION OF MISTS!  •INHALATION Local exhaust or breathing protection. Fresh air, rest.  •SKIN Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower.  •EYES Redness. Pain. Severe deep burns. Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal pain. Burning sensation. Do not eat, drink, or smoke during work. Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention. Rest. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Then remove to safe place. (Extra personal protection: A/P2 filter respirator for organic vapour and harmful dust.) Separated from strong oxidants, and acids. Dry. Xn symbol R: 22-38-41-48/22 S: 2-26-36/37/39-46 SEE IMPORTANT INFORMATION ON BACK ICSC: 0618 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards DIETHANOLAMINE ICSC: 0618 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: WHITE CRYSTALS OR COLOURLESS VISCOUS HYGROSCOPIC LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air. CHEMICAL DANGERS: The substance decomposes on burning producing toxic fumes . The solution in water is a medium strong base. Reacts violently with strong oxidants , strong acids . Attacks copper, zinc, aluminium, and their alloys. OCCUPATIONAL EXPOSURE LIMITS: TLV: 2 mg/m³; (skin); (ACGIH 2002). MAK: 1 mg/m³ (Inhalable fraction) Peak limitation category: I(1) skin absorption (H); sensitization of skin (Sh); Carcinogen category: 3B Pregnancy risk group: C (DFG 2006). OSHA PEL†: none NIOSH REL: TWA 3 ppm (15 mg/m3) NIOSH IDLH: N.D. See: IDLH INDEX ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour and by ingestion. INHALATION RISK: A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is corrosive to the eyes. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the liver and kidneys . PHYSICAL PROPERTIES Boiling point: 269°C Melting point: 28°C Relative density (water = 1): 1.09 (liquid) Solubility in water: very good Vapour pressure, Pa at 20°C: <1 Relative vapour density (air = 1): 3.65 Flash point: 134°C o.c. Auto-ignition temperature: 662°C Explosive limits, vol% in air: 1.7-9.8 Octanol/water partition coefficient as log Pow: -1.43 ENVIRONMENTAL DATA The substance is harmful to aquatic organisms. N O T E S Do NOT take working clothes home. Card has been partly updated in October 2006. See sections: Occupational Exposure Limits, Ingestion First Aid. NFPA Code: H1; F1; R0 ADDITIONAL INFORMATION ICSC: 0618 DIETHANOLAMINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.