International Chemical Safety Cards

FENAMIPHOS ICSC: 0483
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Phenamiphos
Ethyl-3-methyl-4-(methylthio)phenyl(1-methylethyl)phosphoramidate
C13H22NO3PS
Molecular mass: 303.4
6 Poison placard Marine Pollutant placard ICSC #    0483
CAS #     22224-92-6
RTECS # TB3675000
UN #        2783
EC #         015-123-00-5
November 25, 1998 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable.
NO open flames.
Powder . Foam. Carbon dioxide.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Abdominal cramps. Convulsions. Dizziness. Sweating. Nausea. Unconsciousness. Pupillary constriction, muscle cramp, excessive salivation. Symptoms may be delayed (see Notes).
Local exhaust or breathing protection.
Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
 •SKIN MAY BE ABSORBED! (See Inhalation).
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
 •EYES (Further see inhalation.)
Face shield, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION (See Inhalation).
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Do NOT wash away into sewer. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Chemical protection suit including self-contained breathing apparatus.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed.
Do not transport with food and feedstuffs.
Marine pollutant.
T+ symbol
N symbol
R: 24-28-50/53
S: 1/2-23-28-36/37-45-60-61
UN Hazard Class: 6.1
UN Packing Group: I
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0483 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

FENAMIPHOS ICSC: 0483
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PHYSICAL STATE; APPEARANCE:
COLOURLESS CRYSTALS , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
On combustion, forms toxic and corrosive gases.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: (inhalable fraction and vapour) 0.05 mg/m as TWA (skin); A4 (not classifiable as a human carcinogen); BEI issued. (ACGIH 2007).
OSHA PEL: none
NIOSH REL: TWA 0.1 mg/m3 skin
NIOSH IDLH: N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the nervous system , resulting in convulsions and respiratory failure. Cholinesterase inhibitor. Exposure may result in death. The effects may be delayed. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Melting point: 49.2C
Density: 1.15
Solubility in water, g/100 ml: 0.03
Vapour pressure, Pa at 30C: <1
Octanol/water partition coefficient as log Pow: 3.3
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.
N O T E S
Depending on the degree of exposure, periodic medical examination is indicated. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. Bayer 68138, Bay SRA 3886, ENT 27572, Nemacur, Nemacur P, and NSC 195106 are trade names.
Transport Emergency Card: TEC (R)-61G41a
Card has been partially updated in July 2007: see Occupational Exposure Limits, Ingestion First Aid, EU Classification.
Card has been partially updated in January 2008: see Fire fighting.
ADDITIONAL INFORMATION


ICSC: 0483 FENAMIPHOS
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.