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ETHYL IODIDE

ICSC: 0479

Iodoethane
Ethane iodide
Monoiodoethane
C2H5I / CH3CH2I
Molecular mass: 155.97
ICSC #    0479
CAS #     75-03-6
RTECS # KI4750000
April 22, 2004 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Flammable.
NO open flames, NO sparks, and NO smoking.
Powder, water spray, foam, carbon dioxide.
EXPLOSION Above 61°C explosive vapour/air mixtures may be formed.
Above 61°C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


 •INHALATION Confusion. Cough. Drowsiness. Dizziness. Shortness of breath. Sore throat. Unconsciousness.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
 •SKIN Redness. Pain
Protective gloves. Protective clothing.
Rinse skin with plenty of water or shower. Refer for medical attention.
 •EYES Redness. Pain.
Safety goggles, face shield, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Confusion. Dizziness. Drowsiness. Unconsciousness.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Remove all ignition sources. Collect leaking liquid in covered labelled containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Personal protection: filter respirator for organic gases and vapours.
Fireproof. Separated from strong bases, strong oxidants.

ICSC: 0479 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

ETHYL IODIDE

ICSC: 0479

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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. TURNS DARK ON EXPOSURE TO LIGHT.

PHYSICAL DANGERS:
The vapour is heavier than air.

CHEMICAL DANGERS:
The substance decomposes on burning producing iodine and hydrogen iodide . Reacts with strong bases and strong oxidants .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . The substance may cause effects on the central nervous system , resulting in lowering of consciousness .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point: 72°C
Melting point: -108°C
Relative density (water = 1): 1.936
Solubility in water, g/100 ml at 20°C: 0.4
Vapour pressure, kPa at 18°C: 13.3
Relative vapour density (air = 1): 5.4 calculated
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.8
Flash point: 61°C c.c.
Octanol/water partition coefficient as log Pow: 2.0

ENVIRONMENTAL
DATA


N O T E S

Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.

ADDITIONAL INFORMATION



ICSC: 0479 ETHYL IODIDE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
 
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