International Chemical Safety Cards N,N-DIMETHYL-p-TOLUIDINE ICSC: 0456 N,N-Dimethyltoluidine Benzenamine, N,N,4-trimethyl N,N,4-Trimethylaniline C9H13N / CH3C6H4N(CH3)2 Molecular mass: 135.2 ICSC #    0456 CAS #     99-97-8 RTECS # XU5803000 UN #        2810 EC #         612-056-00-9 July 04, 1997 Validated TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Powder, AFFF, foam, carbon dioxide. EXPLOSION Above 83°C explosive vapour/air mixtures may be formed. Above 83°C use a closed system, ventilation. EXPOSURE PREVENT GENERATION OF MISTS! STRICT HYGIENE!  •INHALATION Blue lips or finger nails. Blue skin. Headache. Dizziness. Nausea. Confusion. Convulsions. Unconsciousness. Ventilation. Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.  •SKIN MAY BE ABSORBED! (See Inhalation). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.  •EYES Safety goggles or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION (See Inhalation). Do not eat, drink, or smoke during work. Rinse mouth. Give nothing to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Separated from oxidants food and feedstuffs . Do not transport with food and feedstuffs. Note: C T symbol R: 23/24/25-33-52/53 S: 1/2-28-36/37-45-61 UN Hazard Class: 6.1 SEE IMPORTANT INFORMATION ON BACK ICSC: 0456 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards N,N-DIMETHYL-p-TOLUIDINE ICSC: 0456 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: YELLOW - BROWNISH VISCOUS LIQUID. PHYSICAL DANGERS: CHEMICAL DANGERS: On combustion, forms toxic and corrosive gases (nitrogen oxides). Reacts violently with strong oxidants. Attacks many plastics. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the red blood cells , resulting in formation of methaemoglobin. The effects may be delayed. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 215°C Relative density (water = 1): 0.9 Solubility in water: none Relative vapour density (air = 1): 4.7 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.0 Flash point: 83°C Octanol/water partition coefficient as log Pow: 2.61 ENVIRONMENTAL DATA N O T E S Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. Card has been partly updated in October 2005. See section Emergency Response. Transport Emergency Card: TEC (R)-61GT1-III ADDITIONAL INFORMATION ICSC: 0456 N,N-DIMETHYL-p-TOLUIDINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.