International Chemical Safety Cards

2-DIMETHYLAMINOETHYL METHACRYLATE ICSC: 0450
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Dimethylamino-ethylmethacrylate
N,N-Dimethylaminoethyl methacrylate
Methacrylic acid, 2-(dimethylamino)ethyl ester
C8H15NO2
Molecular mass: 157.2
6 Poison placard ICSC #    0450
CAS #     2867-47-2
RTECS # OZ4200000
UN #        2522
EC #         607-132-00-3
April 04, 2006 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION Above 68C explosive vapour/air mixtures may be formed.
Above 68C use a closed system, ventilation.

EXPOSURE
PREVENT GENERATION OF MISTS!

 •INHALATION Cough. Sore throat.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest.
 •SKIN Skin burns. Pain.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
 •EYES Redness. Pain. Severe deep burns.
Face shield or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Diarrhoea. Nausea. Vomiting. Burning sensation. Shock or collapse.
Do not eat, drink, or smoke during work.
Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: filter respirator for organic gases and vapours. Do NOT let this chemical enter the environment. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Separated from metals , oxidants , strong reducing agents food and feedstuffs . Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access.
Do not transport with food and feedstuffs.
Xn symbol
R: 21/22-36/38-43
S: 2-26-28
UN Hazard Class: 6.1
UN Packing Group: II
Signal: Danger
Corr
Combustible liquid
Causes severe skin burns and eye damage
Harmful to aquatic life
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0450 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

2-DIMETHYLAMINOETHYL METHACRYLATE ICSC: 0450
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PHYSICAL STATE; APPEARANCE:
COLOURLESS TO LIGHT YELLOW LIQUID .

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance may polymerize under the influence of heat , light , oxidants , reducing agents , metals with fire or explosion hazard. The substance decomposes on burning producing toxic fumes including nitrogen oxides . Attacks some forms of rubber.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:


INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is corrosive to the eyes and the skin . The substance is irritating to the respiratory tract . Corrosive on ingestion.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Boiling point: 186C
Melting point: -30C
Relative density (water = 1): 0.93
Solubility in water, g/100 ml at 25C: 10.6
(moderate)
Vapour pressure, kPa at 25C: 0.11
Relative vapour density (air = 1): 5.4
Flash point:
68C c.c.
Auto-ignition temperature: 255C
Explosive limits, vol% in air: 1.2-?
Octanol/water partition coefficient as log Pow: 1.13
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is harmful to aquatic organisms.
N O T E S
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Transport Emergency Card: TEC (R)-61S2522
NFPA Code: H2; F2; R0;
Card has been partially updated in January 2008: see Ingestion First Aid.
ADDITIONAL INFORMATION


ICSC: 0450 2-DIMETHYLAMINOETHYL METHACRYLATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.