International Chemical Safety Cards

TRIS(2,3-DIBROMOPROPYL) PHOSPHATE ICSC: 0433
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
TBPP
2,3-Dibromo-1-propanol phosphate
TDBPP
C9H15Br6O4P
Molecular mass: 697.9
ICSC #    0433
CAS #     126-72-7
RTECS # UB0350000
April 20, 2004 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible under specific conditions.
NO open flames.
Water in large amounts, foam, alcohol-resistant foam, carbon dioxide.
EXPLOSION


EXPOSURE
AVOID ALL CONTACT!

 •INHALATION


 •SKIN
Protective clothing. Protective gloves.
Rinse and then wash skin with water and soap.
 •EYES
Face shield, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: filter respirator for organic gases and vapours. Chemical protection suit. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment.
Separated from food and feedstuffs .

SEE IMPORTANT INFORMATION ON BACK
ICSC: 0433 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

TRIS(2,3-DIBROMOPROPYL) PHOSPHATE ICSC: 0433
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PHYSICAL STATE; APPEARANCE:
VISCOUS COLOURLESS LIQUID .

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating at 200 C producing toxic and corrosive fumes including hydrogen bromide and phosphorous oxides . Reacts with acids and bases .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

EFFECTS OF SHORT-TERM EXPOSURE:


EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
This substance is probably carcinogenic to humans.
PHYSICAL
PROPERTIES
Decomposes below boiling point at 200C
Melting point: 5.5C
Relative density (water = 1): 2.27
g/cm
Solubility in water, g/100 ml at 20C: 0.063
Vapour pressure, Pa at 25C: 0.019
Flash point: > 110C
Octanol/water partition coefficient as log Pow: 4.29
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is toxic to aquatic organisms.
N O T E S
Do NOT take working clothes home. Depending on the degree of exposure, periodic medical examination is suggested.
NFPA Code: H3; F2; R0;
ADDITIONAL INFORMATION


ICSC: 0433 TRIS(2,3-DIBROMOPROPYL) PHOSPHATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.