International Chemical Safety Cards

DIALLYL PHTHALATE ICSC: 0430
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
o-Phthalic acid, diallyl ester
1,2-Benzenedicarboxylic acid, di-2-propenyl ester
DAP
C6H4(CO2CH2CHCH2)2
Molecular mass: 246.3
9 U.S. Miscellaneous placard ICSC #    0430
CAS #     131-17-9
RTECS # CZ4200000
UN #        3082
EC #         607-086-00-4
October 10, 2006 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, carbon dioxide, foam.
EXPLOSION


EXPOSURE
PREVENT GENERATION OF MISTS!

 •INHALATION
Ventilation.
Fresh air, rest.
 •SKIN
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness.
Safety spectacles
Rinse with plenty of water (remove contact lenses if easily possible).
 •INGESTION
Do not eat, drink, or smoke during work.
Rinse mouth.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Ventilation. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment.
Separated from strong oxidants, strong bases, acids. Store only if stabilized. Store in an area without drain or sewer access.

Xn symbol
N symbol
R: 22-50/53
S: 2-24/25-60-61
UN Hazard Class: 9
UN Packing Group: III
Signal: Warning
Excl mark-Enviro
Harmful if swallowed
Harmful if inhaled
May cause allergic skin reaction
Very toxic to aquatic life
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0430 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

DIALLYL PHTHALATE ICSC: 0430
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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance will polymerize due to heating or in the presence of a catalyst, if not inhibited. On combustion, forms toxic gases. Reacts with strong oxidants, acids and bases.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK: IIb (not established but data is available) (DFG 2006).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. 4.4 mg/l x 4 h; 656 (females)-891 (males) mg/kg

INHALATION RISK:
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20C; on spraying or dispersing, however, much faster.

EFFECTS OF SHORT-TERM EXPOSURE:
If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. 1.61 mm2/s (13 cP) at 20 C --> therefore lower viscosity at 40 C (Oct 2006).

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization.
PHYSICAL
PROPERTIES
Boiling point: 290C
Melting point: -70C
Relative density (water = 1): 1.1
Solubility in water, g/100 ml at 20C: 0.015
(very poor)
Vapour pressure, Pa at 25C: 0.02
Relative vapour density (air = 1): 8.3
Flash point:
166C c.c.
Auto-ignition temperature: 385C
Octanol/water partition coefficient as log Pow: 3.23
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. It is strongly advised that this substance does not enter the environment.
N O T E S
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
NFPA Code: H1; F1; R1;
Transport Emergency Card: TEC (R)-90GM6-III
ADDITIONAL INFORMATION


ICSC: 0430 DIALLYL PHTHALATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.