International Chemical Safety Cards

DIBROMOMETHANE ICSC: 0354
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Methylene bromide
Methylene dibromide
CH2Br2
Molecular mass: 173.8
6 Harmful - Stow Away from Foodstuffs placard 6 Poison placard ICSC #    0354
CAS #     74-95-3
RTECS # PA7350000
UN #        2664
EC #         602-003-00-8
October 27, 1995 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible.

In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT GENERATION OF MISTS!

 •INHALATION Dizziness. Drowsiness. Headache. Nausea.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
 •SKIN Dry skin. Redness.
Protective gloves.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
 •EYES Redness.
Safety spectacles or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION (Further see Inhalation).
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Collect leaking and spilled liquid in sealable, non-aluminium containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. Personal protection: A filter respirator for organic gases and vapours.
Separated from food and feedstuffs . Ventilation along the floor.
Do not transport with food and feedstuffs.
Xn symbol
R: 20-52/53
S: 2-24-61
UN Hazard Class: 6.1
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0354 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

DIBROMOMETHANE ICSC: 0354
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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID.

PHYSICAL DANGERS:
The vapour is heavier than air.

CHEMICAL DANGERS:
The substance decomposes on heating, on burning or on contact with hot surfaces producing toxic and irritating fumes including hydrogen bromide .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation.

INHALATION RISK:
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the nervous system and blood , resulting in impaired functions and formation of carboxyhaemoglobinemia. Exposure could cause lowering of consciousness.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The liquid defats the skin. The substance may have effects on the liver and kidneys.
PHYSICAL
PROPERTIES
Boiling point: 97C
Melting point: -52.7C
Relative density (water = 1): 2.5
Solubility in water, g/100 ml at 15C: 1.2
Vapour pressure, kPa at 20C: 5
Relative vapour density (air = 1): 6.0
Relative density of the vapour/air-mixture at 20C (air = 1): 1.25
ENVIRONMENTAL
DATA

N O T E S
Do NOT use in the vicinity of a fire or a hot surface, or during welding. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
Transport Emergency Card: TEC (R)-61GT1-III
ADDITIONAL INFORMATION


ICSC: 0354 DIBROMOMETHANE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.