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TEREPHTHALIC ACID

ICSC: 0330

para-Phthalic acid
1,4-Benzenedicarboxylic acid
C8H6O4 / C6H4(COOH)2
Molecular mass: 166.1
ICSC #    0330
CAS #     100-21-0
RTECS # WZ0875000
April 22, 1994 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Combustible.
NO open flames.
Water spray, foam, powder, carbon dioxide.
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


 •INHALATION Cough.
Local exhaust or breathing protection.
Fresh air, rest.
 •SKIN Redness.
Protective gloves.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
 •EYES Redness.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P2 filter respirator for harmful particles.
Separated from strong oxidants.

ICSC: 0330 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

TEREPHTHALIC ACID

ICSC: 0330

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D

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A

PHYSICAL STATE; APPEARANCE:
WHITE CRYSTALLINE POWDER.

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
Reacts violently with strong oxidants .

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 10 mg/m3 as TWA; (ACGIH 2004).
MAK: 0.1 mg/m3 (Inhalable fraction)
Peak limitation category: I(2) Pregnancy risk group: C
(DFG 2006).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly when dispersed.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes and the skin .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Sublimation point: 402°C
Relative density (water = 1): 1.51
Solubility in water, g/100 ml at 20°C: 0.28
Vapour pressure, Pa at 20°C: <1
Flash point: 260°C
Auto-ignition temperature: 496°C
Octanol/water partition coefficient as log Pow: 1.96

ENVIRONMENTAL
DATA


N O T E S

Card has been partly updated in August 2006. See sections Occupational Exposure Limits.
NFPA Code: H 0; F 1; R 0;

ADDITIONAL INFORMATION



ICSC: 0330 TEREPHTHALIC ACID
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
 
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