International Chemical Safety Cards

FENVALERATE (Technical product) ICSC: 0273
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
(RS)-alpha-Cyano-3-phenoxybenzyl (RS)-2-(4-chlorophenyl)-3-methylbutyrate
Cyano(3-phenoxyphenyl)methyl 4-chloro-alpha-(1-methylethyl)benzeneacetate
C25H22ClNO3
Molecular mass: 419.9
6 Harmful - Stow Away from Foodstuffs placard 6 Poison placard ICSC #    0273
CAS #     51630-58-1
RTECS # CY1576350
UN #        3352
October 19, 2005 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Water , foam , carbon dioxide , powder .
EXPLOSION


EXPOSURE
PREVENT GENERATION OF MISTS! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!

 •INHALATION Burning sensation. Cough. Dizziness. Headache. Nausea.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness. Burning sensation. Numbness. Tingling. Itching.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety goggles, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Nausea. Vomiting. Dizziness. Headache. Convulsions.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: filter respirator for organic gases and vapours. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Store in an area without drain or sewer access. Keep in a well-ventilated room. Separated from strong oxidants, strong bases, food and feedstuffs .
Do not transport with food and feedstuffs.
UN Hazard Class: 6.1
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0273 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

FENVALERATE (Technical product) ICSC: 0273
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PHYSICAL STATE; APPEARANCE:
YELLOW OR BROWN VISCOUS LIQUID

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating between 150-300C producing toxic fumes including hydrogen cyanide , hydrogen chloride . Reacts with strong bases and strong oxidants .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . The substance may cause effects on the nervous system .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization.
PHYSICAL
PROPERTIES
Decomposes below boiling point
Relative density (water = 1): 1.2
Solubility in water:
none
Vapour pressure, Pa at 20C:
negligible
Octanol/water partition coefficient as log Pow: 4.4-6.2
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. This substance may be hazardous in the environment; special attention should be given to honey bees. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
N O T E S
Carrier solvents used in commercial formulations may change physical and toxicological properties. If the substance is formulated with solvents also consult the ICSCs of these materials. Do NOT take working clothes home. Sumicidin, Pydrin, Belmark are trade names. See also ICSC1516 Esfenvalerate.
Transport Emergency Card: TEC (R)-61GT6-III
ADDITIONAL INFORMATION


ICSC: 0273 FENVALERATE (Technical product)
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.