International Chemical Safety Cards

DODECANOYL PEROXIDE ICSC: 0264
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Lauroyl peroxide
Peroxide, didodecanoyl
bis(1-Oxododecyl)peroxide
(C11H23CO)2O2
Molecular mass: 398.7
5.2 Organic Peroxide placard ICSC #    0264
CAS #     105-74-8
RTECS # OF2625000
UN #        3106
EC #         617-003-00-3
March 24, 1999 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Flammable.
NO open flames, NO sparks, and NO smoking.
Water in large amounts, water spray.
EXPLOSION Risk of fire and explosion on contact with combustible substances, reducing agents and at warming.
Prevent warming above 25C.
In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.
EXPOSURE
PREVENT DISPERSION OF DUST!

 •INHALATION Cough. Sore throat.
Local exhaust or breathing protection.
Fresh air, rest.
 •SKIN Redness. Pain.
Protective gloves.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety goggles or face shield .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Evacuate danger area in case of large spills! Consult an expert! Remove all ignition sources. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT absorb in saw-dust or other combustible absorbents. Personal protection: P2 filter respirator for harmful particles.
Fireproof. Separated from combustible and reducing substances. Cool.

O symbol
R: 7
S: 2-3/7-14-36-37/39
UN Hazard Class: 5.2
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0264 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

DODECANOYL PEROXIDE ICSC: 0264
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PHYSICAL STATE; APPEARANCE:
WHITE POWDER OR SOLID IN VARIOUS FORMS.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
Heating may cause violent combustion or explosion. The substance is a strong oxidant and reacts with combustible and reducing materials, causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol.

INHALATION RISK:
Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

EFFECTS OF SHORT-TERM EXPOSURE:
The aerosol is irritating to the eyes , the skin and the respiratory tract .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Melting point: 49-57C
Density: 0.9
g/cm
Solubility in water:
none
Auto-ignition temperature: 112C
ENVIRONMENTAL
DATA

N O T E S
Laurox W 40, Alperox, LYP97 are trade names. Other UN number for water solution (<42%): 3109. Card has been partly updated in October 2005. See sections EU classification, Emergency Response. Card has been partly updated in October 2006. See Ingestion First Aid.
Transport Emergency Card: TEC (R)-52GP1-S

NFPA Code: H0; F2; R3; OX
ADDITIONAL INFORMATION


ICSC: 0264 DODECANOYL PEROXIDE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.